The Mechanism of Oxygen Incorporation into the Products of Acrolein Oxidation over H3PMo12O40 and K3PMo12O40 | Sciact - CRIS-system of Boreskov Institute of Catalysis

The Mechanism of Oxygen Incorporation into the Products of Acrolein Oxidation over H3PMo12O40 and K3PMo12O40 Full article

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 1994, Volume: 35, Number: 1, Pages: 80-83 Pages count : 4

Authors

Popova G.Ya. ¹ , Andrushkevich T.V. ¹ , Bondareva V.M. ¹ , Zakharov I.I. ¹

Affiliations

1	Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090 Russia

The mechanism of oxygen incorporation into the products of acrolein oxidation over H3PMo12O40 and K3PMo12O40 is studied. It is shown that acrylic acid and carbon oxides are formed by a redox mechanism. Higher rates of acrylic-acid formation on reduced heteropolycompounds are accounted for by different mechanisms of acrolein activation on oxidized and reduced surfaces.

Popova G.Y. , Andrushkevich T.V. , Bondareva V.M. , Zakharov I.I.
The Mechanism of Oxygen Incorporation into the Products of Acrolein Oxidation over H3PMo12O40 and K3PMo12O40
Kinetics and Catalysis. 1994. V.35. N1. P.80-83. WOS РИНЦ

Попова Г.Я. , Андрушкевич Т.В. , Бондарева В.М. , Захаров И.И.
Механизм внедрения кислорода в продукты окисления акролеина на H3PMo12O40 и K3PMo12O40
Кинетика и катализ. 1994. Т.35. №1. С.91-95. РИНЦ ANCAN

Submitted:

Dec 26, 1992

Web of science:	WOS:A1994NE85400012
Elibrary:	30596006

DB	Citing
Web of science	1
Elibrary	1