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Synthesis of Higher Alcohols on Cu-Co-Al Catalysts. Dependences on the Composition and Structure of Precursors Научная публикация

Журнал Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Вых. Данные Год: 1995, Том: 36, Номер: 6, Страницы: 810-815 Страниц : 6
Авторы Volkova G.G. 1 , Yur'eva T.M. 1 , Plyasova L.M. 1
Организации
1 Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090 Russia

Реферат: Catalytic properties of Cu-Co-Al oxide compounds of various phase compositions in the direct synthesis of higher alcohols from synthesis gas ate studied. Three regions differing in their product compositions are found; higher alcohols are formed preferentially in the 290 - 350 °C temperature range. The activity and selectivity of the obtained catalysts depend on the calcination temperature; higher alcohols are formed only on the low-temperature samples. It was shown by means of XPS and thermal analysis that at low temperatures (below 500 °C), the compounds of two types with the spinel and delafossite structures could be formed in this oxide system; their behavior in the synthesis of alcohols differs significantly The ratio of these compounds determines the catalytic properties of Cu-Co-Al samples of any composition.
Библиографическая ссылка: Volkova G.G. , Yur'eva T.M. , Plyasova L.M.
Synthesis of Higher Alcohols on Cu-Co-Al Catalysts. Dependences on the Composition and Structure of Precursors
Kinetics and Catalysis. 1995. V.36. N6. P.810-815. WOS РИНЦ CAPlusCA
Оригинальная: Волкова Г.Г. , Юрьева Т.М. , Плясова Л.М.
Синтез высших спиртов на Cu-Co-Al-катализаторах. Зависимости от состава и структуры соединения-предшественника
Кинетика и катализ. 1995. Т.36. №6. С.883-888. РИНЦ
Даты:
Поступила в редакцию: 19 авг. 1994 г.
Идентификаторы БД:
Web of science: WOS:A1995TR97900014
РИНЦ: 29283679
Chemical Abstracts: 1996:74746
Chemical Abstracts (print): 124:120733
Цитирование в БД:
БД Цитирований
Web of science 2
РИНЦ 1