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Role of Support in Adsorption and Catalysis on Supported Metals. 1. IR Spectroscopic Study of Adsorption of CO and H2 on Rh/SiO2, Rh/Al2O3, and Rh/La2O3 Full article

Journal Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Output data Year: 1987, Volume: 28, Number: 3, Pages: 585-591 Pages count : 7
Tags CARBON MONOXIDE - Adsorption; HYDROGEN - Adsorption; RHODIUM COMPOUNDS
Authors Bredikhin M.N. 1 , Lokhov Y.A. 1 , Kuznetsov V.L. 1
Affiliations
1 Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR

Abstract: With the aim of studying the influence of the nature of the support on the properties of supported rhodium-containing catalysts, the adsorption of CO and H2 on Rh/SiO2, Rh/Al2O3, and Rh/La2O3 has been investigated. It has been found that in the case of Rh/La2O3, along with the surface complexes that are characteristic for Rh/SiO2 and Rh/Al2O3, new surface compounds of adsorbed CO and H2 are formed. On the basis of an analysis of the spectrochemical properties of these compounds, it has been concluded that they are formed at the metal/substrate boundary with the participation of the metal atoms and also the atoms of the support.
Cite: Bredikhin M.N. , Lokhov Y.A. , Kuznetsov V.L.
Role of Support in Adsorption and Catalysis on Supported Metals. 1. IR Spectroscopic Study of Adsorption of CO and H2 on Rh/SiO2, Rh/Al2O3, and Rh/La2O3
Kinetics and Catalysis. 1987. V.28. N3. P.585-591. WOS Scopus РИНЦ
Original: Бредихин М.Н. , Лохов Ю.А. , Кузнецов В.Л.
Роль носителя в адсорбции и катализе на нанесенных металлах. I. ИК-спектроскопическое изучение адсорбции CO и H2 на Rh/SiO2, Rh/Al2O3 и Rh/La2O3
Кинетика и катализ. 1987. Т.28. №3. С.671-677. РИНЦ ANCAN
Dates:
Submitted: Jun 6, 1985
Published print: May 1, 1987
Identifiers:
Web of science: WOS:A1987L779800005
Scopus: 2-s2.0-0023343227
Elibrary: 23623866
Citing:
DB Citing
Web of science 3
Scopus 3
Elibrary 2