Relationship Between Molecularity and Activation-Energy of Reversible-Reaction | Sciact - CRIS-system of Boreskov Institute of Catalysis

Relationship Between Molecularity and Activation-Energy of Reversible-Reaction Full article

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 1989, Volume: 30, Number: 4 pt 1, Pages: 703-708 Pages count : 6

Authors

Gerasev A.P. ¹

Affiliations

1	Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR

The general form of the kinetic equation for a complex, reversible, single-path reaction with a rate-determining step is analyzed. A relation is found between molecularity and apparent activation energy at the optimum reaction temperature. When the kinetic equation for the forward (reverse) reaction can be represented in a form with separation of the variables T (temp.) and P (vector for reagent partial pressures), the molecularity and activation energy can be calculated This approach was used to treat kinetic data for SO2 oxidation on V catalysts.

Gerasev A.P.
Relationship Between Molecularity and Activation-Energy of Reversible-Reaction
Kinetics and Catalysis. 1989. V.30. N4 pt 1. P.703-708. WOS РИНЦ

Герасев А.П.
Соотношение между молекулярностью и энергией активации обратимой реакции
Кинетика и катализ. 1989. Т.30. №4. С.803-808. РИНЦ ANCAN

Submitted:	Mar 22, 1988
Published print:	Jul 1, 1989

Web of science:	WOS:A1989CW51300006
Elibrary:	24497502

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