Studies of Catalysts for the Oxidative Ammonolysis of Propane. III. Phase Composition and Catalytic Properties of a Gallium-Antimony System with Phosphorus | Sciact - CRIS-system of Boreskov Institute of Catalysis

Studies of Catalysts for the Oxidative Ammonolysis of Propane. III. Phase Composition and Catalytic Properties of a Gallium-Antimony System with Phosphorus Full article

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 1991, Volume: 31, Number: 5 pt 2, Pages: 1118-1122 Pages count : 5

Tags

Acrylic Monomers--Synthesis; Phosphorus--Effects; Propane--Oxidation; Spectroscopy, Photoelectron--Applications; Surfaces--Analysis

Authors

Bury'lin S.Y. ¹ , Osipova Z.G. ¹ , Sokolovskii V.D. ¹ , Kalinkin A.V. ¹ , Pashis A.V. ¹ , Shubin A.A. ¹ , Olenʹkova I.P. ¹

Affiliations

1	Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR

The effect of phosphorus on the phase and surface composition, and catalytic properties of gallium-antimony catalyst samples has been studied by x-ray phase analysis (XPA), x-ray photoelectron spectroscopy (XPES), and NMR. It was found that the phosphorus in these samples is nonhomogeneous or nonuniform. The majority of the phosphorus is present in the form of gallium phosphate, but a minor amount is bound to gallium antimonate. As the total amount of phosphorus is increased the concentration of each of these forms is also increased, and the rate constant for dioxidation to acrylonitrile (AN) is reduced, due to surface modification of gallium antimonate by phosphorus, which binds excess gallium (relative to the antimonate) present on the surface of catalysts without phosphorus.

Bury'lin S.Y. , Osipova Z.G. , Sokolovskii V.D. , Kalinkin A.V. , Pashis A.V. , Shubin A.A. , Olenʹkova I.P.
Studies of Catalysts for the Oxidative Ammonolysis of Propane. III. Phase Composition and Catalytic Properties of a Gallium-Antimony System with Phosphorus
Kinetics and Catalysis. 1991. V.31. N5 pt 2. P.1118-1122. WOS Scopus РИНЦ

Бурылин С.Ю. , Осипова З.Г. , Соколовский В.Д. , Калинкин А.В. , Пашис А.В. , Шубин А.А. , Оленькова И.П.
Исследование катализаторов окислительного аммонолиза пропана. III. Фазовый состав и каталитические свойства галлийсурьмяной системы с фосфором
Кинетика и катализ. 1990. Т.31. №5. С.1271-1276. РИНЦ ANCAN

Submitted:	May 3, 1989
Published print:	Apr 1, 1991

Web of science:	WOS:A1990FM58000024
Scopus:	2-s2.0-0026142568
Elibrary:	31076177

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