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Mechanism of Ziegler-Natta Polymerization on the Basis of Data on the Number of Active Centers and Their Reactivity Full article

Conference Symposium on coordination polymerization: American Chemical Society meeting
30-30 Mar 1981 , Atlanta, Georgia
Source Coordination polymerization
Compilation, Plenum Press. New York.1983. 331 c. ISBN 9781461335771. РИНЦ
Journal Polymer Science and Technology: A Symposia Series
ISSN: 0093-6286
Output data Year: 1983, Volume: 19, Pages: 267-288 Pages count : 22 DOI: 10.1007/978-1-4613-3575-7_14
Authors Zakharov V.A. 1 , Bukatov G.D. 1 , Yermakov Yu.I. 1
Affiliations
1 Institute of Catalysis, Novosibirsk, 630090, USSR

Abstract: Quantitative data on the number of active centers are very informative for the formulation of concepts on mechanism of catalytic polymerization and for interpretation of polymerization kinetics. Systematic study of the effect of the catalyst composition and the polymerization conditions on the number of active centers and their reactivity (rate constants of different steps of overall polymerization process) is important for understanding: i) the role of various components of catalytic system in the formation of active centers; ii)the plausible composition of active centers; iii)the mechanism of separate polymerization steps; iv)the possible reasons for the increased activity of supported catalysts in comparison with conventional Ziegler-Natta catalysts.
Cite: Zakharov V.A. , Bukatov G.D. , Yermakov Y.I.
Mechanism of Ziegler-Natta Polymerization on the Basis of Data on the Number of Active Centers and Their Reactivity
In compilation Coordination polymerization. – Plenum Press., 1983. – C.267-288. – ISBN 9781461335771. DOI: 10.1007/978-1-4613-3575-7_14 РИНЦ ANCAN OpenAlex
Identifiers:
Elibrary: 46491472
Chemical Abstracts: 1983:89941
Chemical Abstracts (print): 98:89941
OpenAlex: W2236407856
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