195Pt and 119Sn NMR Studies of H2PtCl6 Interaction with SnCl2 in Isopropanol Full article
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Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Output data | Year: 1983, Volume: 23, Number: 1-2, Pages: 17-20 Pages count : 4 DOI: 10.1007/BF02065656 | ||
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Abstract:
According to 195Pt and 119Sn NMR studies, it is shown that in isopropanol solution of H2PtCl6+SnCl2+HCl, successive reactions take place: first, rapid H2PtCl6 reduction involving the participation of both SnCl2 and isopropanol, then the formation of Pt−Sn complexes with Sn(II):Pt(II)=1 and 2 and an intermediate complex with Sn(II):Pt(II)=5. Variations in the composition of the solutions have been quantitatively estimated.
Методом ЯМР 195Pt и 119Sn показано, что в изопропанольном растворе H2PtCl6+SnCl2+HCl во времени протекают следующие последовательные реакции: быстрое восстановление H2PtCl6 с участием как SnCl2, так и изопропанола и образование платинооловянных комплесов с соотношением Sn(II):Pt(II)=1 и 2 через промежуточный комплекс с соотношением Sn(II):Pt(II)=5. Дана количественная оценка изменения состава Pt−Sn-комплексов во времени.
Cite:
Shitova N.B.
, Alt L.Y.
, Perevalova V.I.
, Belyi A.S.
, Duplyakin V.K.
195Pt and 119Sn NMR Studies of H2PtCl6 Interaction with SnCl2 in Isopropanol
Reaction Kinetics and Catalysis Letters. 1983. V.23. N1-2. P.17-20. DOI: 10.1007/BF02065656 WOS Scopus РИНЦ ANCAN OpenAlex
195Pt and 119Sn NMR Studies of H2PtCl6 Interaction with SnCl2 in Isopropanol
Reaction Kinetics and Catalysis Letters. 1983. V.23. N1-2. P.17-20. DOI: 10.1007/BF02065656 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Oct 1, 1982 |
| Accepted: | Jan 13, 1983 |
| Published print: | Mar 1, 1983 |
| Published online: | Aug 3, 2013 |
Identifiers:
| Web of science: | WOS:A1983SB83400004 |
| Scopus: | 2-s2.0-0343207456 |
| Elibrary: | 31108946 |
| Chemical Abstracts: | 1984:92203 |
| Chemical Abstracts (print): | 100:92203 |
| OpenAlex: | W2016447563 |