Allylic Oxdation of Alkenes with Molecular Oxygen Catalyzed by Porous Coordination Polymers Fe-MIL-101 and Cr-MIL-101 Full article
| Conference |
IX International Conference “Mechanisms of Catalytic Reactions” 22-25 Oct 2012 , Санкт-Петербург |
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| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2013, Volume: 54, Number: 5, Pages: 607-614 Pages count : 8 DOI: 10.1134/S0023158413050169 | ||||||
| Tags | alkenes, allylic oxidation, MIL-101, molecular oxygen, porous coordination polymers, terpenes | ||||||
| Authors |
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| Affiliations |
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Funding (5)
| 1 | Institute of Researches on Catalysis and Environment in Lyon | |
| 2 | Russian Foundation for Basic Research | 09-03-93109 |
| 3 | Russian Foundation for Basic Research | 13-03-00314 |
| 4 | French National Centre for Scientific Research | |
| 5 | French Embassy in Moscow |
Abstract:
The catalytic performances of Cr-MIL-101 and Fe-MIL-101 porous coordination polymers have been investigated in the allylic oxidation of alkenes, including natural terpenes, with molecular oxygen (1 atm) under mild solvent-free conditions. Both catalysts remain stable under optimal conditions (40°C for Fe-MIL-101 and 60°C for Cr-MIL-101) and can be recycled, at least, four times without loss of the catalytic properties. Fe-MIL-101 favours the formation of unsaturated alcohols, while Cr-MIL-101 mediates the formation of unsaturated ketones. The oxidation process involves the formation of alkene hydroperoxide via conventional radical chain process and its further transformations over the MIL-101 catalysts. The mechanism of the hydroperoxide transformation strongly depends on the metal nature.
Cite:
Skobelev I.Y.
, Kovalenko K.A.
, Fedin V.P.
, Sorokin A.B.
, Kholdeeva O.A.
Allylic Oxdation of Alkenes with Molecular Oxygen Catalyzed by Porous Coordination Polymers Fe-MIL-101 and Cr-MIL-101
Kinetics and Catalysis. 2013. V.54. N5. P.607-614. DOI: 10.1134/S0023158413050169 WOS Scopus РИНЦ ANCAN OpenAlex
Allylic Oxdation of Alkenes with Molecular Oxygen Catalyzed by Porous Coordination Polymers Fe-MIL-101 and Cr-MIL-101
Kinetics and Catalysis. 2013. V.54. N5. P.607-614. DOI: 10.1134/S0023158413050169 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Скобелев И.Ю.
, Коваленко К.А.
, Федин В.П.
, Сорокин А.Б.
, Холдеева О.А.
Аллильное окисление алкенов молекулярным кислородом, катализируемое пористыми координационными полимерами Fe-MIL-101 и Cr-MIL-101
Кинетика и катализ. 2013. Т.54. №5. С.641-648. DOI: 10.7868/S045388111305016X РИНЦ OpenAlex
Аллильное окисление алкенов молекулярным кислородом, катализируемое пористыми координационными полимерами Fe-MIL-101 и Cr-MIL-101
Кинетика и катализ. 2013. Т.54. №5. С.641-648. DOI: 10.7868/S045388111305016X РИНЦ OpenAlex
Dates:
| Published print: | Sep 1, 2013 |
| Published online: | Sep 27, 2013 |
Identifiers:
| Web of science: | WOS:000325023200012 |
| Scopus: | 2-s2.0-84885406487 |
| Elibrary: | 21466967 |
| Chemical Abstracts: | 2013:1529533 |
| Chemical Abstracts (print): | 159:640704 |
| OpenAlex: | W2073730904 |