Phase-Transfer Oxidation of 2-Methyl-1-Naphthol into 2-Methyl-1,4-Naphthoquinone in the Presence of Vanadomolybdophosphoric Heteropolyacids | Sciact - CRIS-system of Boreskov Institute of Catalysis

Phase-Transfer Oxidation of 2-Methyl-1-Naphthol into 2-Methyl-1,4-Naphthoquinone in the Presence of Vanadomolybdophosphoric Heteropolyacids Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 1994, Volume: 43, Number: 7, Pages: 1142-1145 Pages count : 4 DOI: 10.1007/BF00698232

Tags

2-methyl-1,4-naphthoqumone, 2-methyl-1-naphthol, heteropolyacids, oxidation, phase-transfer catalysis

Authors

Matveev K.I. ¹ , Zhizhina E.G. ¹ , Odyakov V.F. ¹ , Parmon V.N. ¹

Affiliations

1	G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences

2-Methyl-1-naphthol is oxidized into 2-methyl-1,4-naphthoquinone (menadione) by air in the presence of vanadomolybdophosphoric heteropolyacids and their salts. The reaction proceeds in a biphasic system, and the yield of menadione is up to 85 %. The influence of the composition of the heteropolyacids on the rate and the selectivity of the reaction was studied, and the reaction mechanism was proposed.

Matveev K.I. , Zhizhina E.G. , Odyakov V.F. , Parmon V.N.
Phase-Transfer Oxidation of 2-Methyl-1-Naphthol into 2-Methyl-1,4-Naphthoquinone in the Presence of Vanadomolybdophosphoric Heteropolyacids
Russian Chemical Bulletin. 1994. V.43. N7. P.1142-1145. DOI: 10.1007/BF00698232 WOS Scopus РИНЦ OpenAlex

Матвеев К.И. , Жижина Е.Г. , Одяков В.Ф. , Пармон В.Н.
Окисление 2-метил-1-нафтола в 2-метил-1,4-нафтохинон методом межфазного катализа в присутствии ванадомолибдофосфорных гетерополикислот
Известия Академии наук. Серия химическая. 1994. №7. С.1208-1211. РИНЦ ANCAN

Submitted:	Jul 26, 1993
Published print:	Jul 1, 1994

Web of science:	WOS:A1994QK21800007
Scopus:	2-s2.0-11544295498
Elibrary:	31101577
OpenAlex:	W2073995871

DB	Citing
Web of science	3
Scopus	6
Elibrary	5
OpenAlex	7