Carbon-Supported Palladium Catalysts. Some Aspects of Preparation in Connection with the Adsorption Properties of the Supports Full article
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Scientific Bases for the Preparation of Heterogeneous Catalysts : the Fifth International Symposium 03-06 Sep 1990 , Louvain-la-Neuve |
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| Source | Preparation of Catalysts V. Scientific Bases for the Preparation of Heterogeneous Catalysts : Proceedings of the Fifth International Symposium,
3-6 September 1990, Louvain-la-Neuve Compilation, 1991. 748 c. ISBN 9780444886163. |
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| Journal |
Studies in Surface Science and Catalysis
ISSN: 0167-2991 |
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| Output data | Year: 1991, Volume: 63, Pages: 449-458 Pages count : 10 DOI: 10.1016/S0167-2991(08)64607-8 | ||
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Abstract:
Adsorption of metal complexes on carbon supports can be accompanied by ligand-exchange involving intrinsic π-fragments of carbon framework. The size of metal crystallites derived from carbon-adsorbed species does not correlate with the proportion of metal accessible to carbon monoxide and reagents of catalytic reaction; this suggests blocking a part of the metallic surface by walls of the support pores. Appropriate choice of the support, metal precursor and procedures at the deposition step makes it possible to eliminate or, at least, diminish such a detrimental effect and to control the size, shape, sites of location, distribution along the catalyst grain and, thus, catalytic properties of final metal crystallites. A strightforward use of carbon-adsorbed complexes as heterogenized catalysts is also discussed.
Cite:
Lisitsyn A.S.
, Simonov P.A.
, Ketterling A.A.
, Likholobov V.A.
Carbon-Supported Palladium Catalysts. Some Aspects of Preparation in Connection with the Adsorption Properties of the Supports
In compilation Preparation of Catalysts V. Scientific Bases for the Preparation of Heterogeneous Catalysts : Proceedings of the Fifth International Symposium, 3-6 September 1990, Louvain-la-Neuve. 1991. – C.449-458. – ISBN 9780444886163. DOI: 10.1016/S0167-2991(08)64607-8 WOS Scopus РИНЦ OpenAlex OpenAlex ANCAN
Carbon-Supported Palladium Catalysts. Some Aspects of Preparation in Connection with the Adsorption Properties of the Supports
In compilation Preparation of Catalysts V. Scientific Bases for the Preparation of Heterogeneous Catalysts : Proceedings of the Fifth International Symposium, 3-6 September 1990, Louvain-la-Neuve. 1991. – C.449-458. – ISBN 9780444886163. DOI: 10.1016/S0167-2991(08)64607-8 WOS Scopus РИНЦ OpenAlex OpenAlex ANCAN
Dates:
| Published print: | Jan 1, 1991 |
| Published online: | Aug 22, 2008 |
Identifiers:
| ≡ Web of science: | WOS:A1991BU17D00040 |
| ≡ Scopus: | 2-s2.0-0012251125 |
| ≡ Elibrary: | 27246125 |
| ≡ OpenAlex: | W185939605 | W4241383770 |
| ≡ Chemical Abstracts: | 1991:590717 |
| ≡ Chemical Abstracts (print): | 115:190717 |