Structure, Composition and Activity of Supported Titanium-Magnesium Catalysts for Ethylene Polymerization Full article
| Conference |
Catalytic Polymerizatlon of Olefins : International Symposium on Future Aspects of Olefin Polymerization 04-06 Jul 1985 , Tokyo |
||
|---|---|---|---|
| Source | Catalytic Polymerizatlon of Olefins : Proceedings of the International Symposium on Future Aspects of Olefin Polymerization, 4-6 July 1985, Tokyo, Japan Compilation, Elsevier B.V.. Amsterdam.1986. 489 c. ISBN 9780444995186. |
||
| Journal |
Studies in Surface Science and Catalysis
ISSN: 0167-2991 |
||
| Output data | Year: 1986, Volume: 25, Pages: 71-89 Pages count : 19 DOI: 10.1016/S0167-2991(09)60320-7 | ||
| Authors |
|
||
| Affiliations |
|
Abstract:
Studied is the effect of the substructure of magnesium chloride on the composition and activity of Ti-Mg catalysts prepared by different methods: (i) adsorption of TiCl4, on highly dispersed magnesium chloride prepared from nonsolvated buthylmagnesiumchloride, (ii) adsorption of TiCl4 on magnesium chloride activated by milling, and (iii) co-milling of magnesium chloride with TiCl4. TiCl4 is shown to react with the defects of the magnesium chloride structure. The concentration of these defects is associated with the size of the coherent scattering range, which is determined from X-ray data. Evidences have been obtained that the surface of magnesium chloride is nonuniform with respect to the interaction with TiCl4 and VCl4, The resulting V4+, Ti4+ and Ti3+ surface compounds also are nonuniform in the coordination state and catalytic properties. The state of Ti3+ ions after the interaction of Ti-Mg catalysts with trialkyl-aluminum has been examined. It is assumed that active centers of these systems are in the surface associates of Ti3+ ions.
Cite:
Zakharov V.A.
, Makhtarulin S.I.
, Perkovets D.V.
, Moroz E.M.
, Mikenas T.B.
, Bukatov G.D.
Structure, Composition and Activity of Supported Titanium-Magnesium Catalysts for Ethylene Polymerization
In compilation Catalytic Polymerizatlon of Olefins : Proceedings of the International Symposium on Future Aspects of Olefin Polymerization, 4-6 July 1985, Tokyo, Japan. – Elsevier B.V.., 1986. – C.71-89. – ISBN 9780444995186. DOI: 10.1016/S0167-2991(09)60320-7 Scopus РИНЦ ANCAN OpenAlex
Structure, Composition and Activity of Supported Titanium-Magnesium Catalysts for Ethylene Polymerization
In compilation Catalytic Polymerizatlon of Olefins : Proceedings of the International Symposium on Future Aspects of Olefin Polymerization, 4-6 July 1985, Tokyo, Japan. – Elsevier B.V.., 1986. – C.71-89. – ISBN 9780444995186. DOI: 10.1016/S0167-2991(09)60320-7 Scopus РИНЦ ANCAN OpenAlex
Dates:
| Published print: | Jan 1, 1986 |
| Published online: | Jan 4, 2009 |
Identifiers:
| Scopus: | 2-s2.0-0022957754 |
| Elibrary: | 31009359 |
| Chemical Abstracts: | 1986:443441 |
| Chemical Abstracts (print): | 105:43441 |
| OpenAlex: | W91207049 |