HREELS/TDS Identification of Intermediates in The Low-Temperature H2+O2, NO+H2, NH3+O2 Reactions on Pt(111) Surface Full article
| Conference |
New Frontiers in Catalysis : 10th International Congress on Catalysis 19-24 Jul 1992 , Budapest |
||
|---|---|---|---|
| Source | New Frontiers in Catalysis : Proceedings of the 10th International Congress on Catalysis, Budapest, 19-24 July 1992 Compilation, Elsevier. Amsterdam-London-New York-Tokyo.1993. 2859 c. |
||
| Journal |
Studies in Surface Science and Catalysis
ISSN: 0167-2991 |
||
| Output data | Year: 1993, Volume: 75, Pages: 1587-1590 Pages count : 4 DOI: 10.1016/S0167-2991(08)64486-9 | ||
| Authors |
|
||
| Affiliations |
|
Abstract:
There is a possibility of the formation of different products during NO reduction with hydrogen and NH3 oxidation depending on the conditions and the metals used. The character of the NO adsorbed state (molecular or dissociative) determines the formation of the key product (NH3 or N2). The activity of Pt toward breaking the N–O bond is very sensitive to the surface structure. The study of low-temperature oxidative catalysis described in the chapter establishes the mechanisms of the reactions proceeding with the participation of the reactants in the molecularly adsorbed states. In the study described in the chapter, high resolution electron energy loss spectroscopy (HREELS) and thermal desorption spectroscopy (TDS) were used for the study of the low-temperature adsorption of H2, O2, NO, and NH3 and the H2 + O2, NO + H2, and NH3 + O2 reactions on the Pt(III) surface. Experiments were carried out by VG ADES-400 spectrometer, and the monochromatic electron beam with a kinetic energy of 2.5 eV and resolution of 10 meV (80 cm−1) was used.
Cite:
Gorodetskii V.V.
, Smirnov M.Y.
, Cholach A.R.
HREELS/TDS Identification of Intermediates in The Low-Temperature H2+O2, NO+H2, NH3+O2 Reactions on Pt(111) Surface
In compilation New Frontiers in Catalysis : Proceedings of the 10th International Congress on Catalysis, Budapest, 19-24 July 1992. – Elsevier., 1993. – Т.1-3. – C.1587-1590. DOI: 10.1016/S0167-2991(08)64486-9 WOS WOS Scopus РИНЦ ANCAN OpenAlex
HREELS/TDS Identification of Intermediates in The Low-Temperature H2+O2, NO+H2, NH3+O2 Reactions on Pt(111) Surface
In compilation New Frontiers in Catalysis : Proceedings of the 10th International Congress on Catalysis, Budapest, 19-24 July 1992. – Elsevier., 1993. – Т.1-3. – C.1587-1590. DOI: 10.1016/S0167-2991(08)64486-9 WOS WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Published print: | Jan 1, 1993 |
| Published online: | Jun 3, 2008 |
Identifiers:
| Web of science: | WOS:A1993MK93200064 | WOS:A1993BZ35J00064 |
| Scopus: | 2-s2.0-0343187805 |
| Elibrary: | 29830765 |
| Chemical Abstracts: | 1993:679849 |
| Chemical Abstracts (print): | 119:279849 |
| OpenAlex: | W1123167568 |