Mechanism of FeZSM-5 Milling and Its Effect on the Catalytic Performance in Benzene to Phenol oxidation Full article
| Journal |
Zeolites
ISSN: 0144-2449 |
||
|---|---|---|---|
| Output data | Year: 1995, Volume: 15, Number: 3, Pages: 253-258 Pages count : 6 DOI: 10.1016/0144-2449(94)00019-O | ||
| Tags | ball milling, amorphization, benzene oxidation, N2O, crystallinity, catalytic activity, FeZSM-5 | ||
| Authors |
|
||
| Affiliations |
|
Abstract:
The mechanism of milling ZSM-5 ferrisilicate analog in the centrifugal planetary mill was studied by means of adsorption, electron microscopy, and X-ray diffraction. The process of zeolite lattice destruction obeyed a first-order kinetic equation. The 40-min milling resulted in a practically complete amorphization of the material and disappearence of its catalytic activity in oxidation of benzene to phenol by dinitrogen monoxide.
The reaction was shown to proceed in the intercrystalline channel space. Amorphous phase formed upon milling was found to be catalytically inactive.
Cite:
Kharitonov A.S.
, Fenelonov V.B.
, Voskresenskaya T.P.
, Rudina N.A.
, Molchanov V.V.
, Plyasova L.M.
, Panov G.I.
Mechanism of FeZSM-5 Milling and Its Effect on the Catalytic Performance in Benzene to Phenol oxidation
Zeolites. 1995. V.15. N3. P.253-258. DOI: 10.1016/0144-2449(94)00019-O WOS Scopus РИНЦ ANCAN OpenAlex
Mechanism of FeZSM-5 Milling and Its Effect on the Catalytic Performance in Benzene to Phenol oxidation
Zeolites. 1995. V.15. N3. P.253-258. DOI: 10.1016/0144-2449(94)00019-O WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Apr 3, 1994 |
| Published print: | Mar 1, 1995 |
| Published online: | May 21, 1998 |
Identifiers:
| Web of science: | WOS:A1995QP52000011 |
| Scopus: | 2-s2.0-0029277690 |
| Elibrary: | 31099908 |
| Chemical Abstracts: | 1995:487508 |
| Chemical Abstracts (print): | 122:223793 |
| OpenAlex: | W2054130712 |