FTIR Study of the Surface Complexes of β-Picoline, 3-Pyridine-Carbaldehyde and Nicotinic Acid on Sulfated TiO2 (Anatase) Научная публикация
| Журнал |
Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
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| Вых. Данные | Год: 2013, Том: 373, Страницы: 96-107 Страниц : 12 DOI: 10.1016/j.molcata.2013.03.007 | ||
| Ключевые слова | β-Picoline, 3-Pyridine-carbaldehyde, FTIR, Nicotinic acid, Sulfated anatase | ||
| Авторы |
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| Организации |
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Реферат:
Surface complexes of β-picoline, 3-pyridine-carbaldehyde and nicotinic acid on sulfated TiO2 (anatase) containing 0.12 and 6.9 wt.% SO42− were studied using FTIR spectroscopy. The water and β-picoline were used as molecular probes for identification of surface acidity and sulfate species. Depending on SO42− content, FTIR spectra have revealed differences in the type, quantity and strength of acidic sites as well as in the composition and strength of surface complexes of β-picoline, 3-pyridine-carbaldehyde and nicotinic acid. Both samples possess Lewis and Bronsted acidic sites. But only TiO2 (6.9) contains strong Bronsted sites. On this sample the dead-end nicotinates form during 3-pyridine-carbaldehyde transformation while the weakly bound nicotinates on TiO2 (0.12) surface transform into nicotinic acid.
Библиографическая ссылка:
Chesalov Y.A.
, Chernobay G.B.
, Andrushkevich T.V.
FTIR Study of the Surface Complexes of β-Picoline, 3-Pyridine-Carbaldehyde and Nicotinic Acid on Sulfated TiO2 (Anatase)
Journal of Molecular Catalysis A: Chemical. 2013. V.373. P.96-107. DOI: 10.1016/j.molcata.2013.03.007 WOS Scopus РИНЦ CAPlusCA OpenAlex
FTIR Study of the Surface Complexes of β-Picoline, 3-Pyridine-Carbaldehyde and Nicotinic Acid on Sulfated TiO2 (Anatase)
Journal of Molecular Catalysis A: Chemical. 2013. V.373. P.96-107. DOI: 10.1016/j.molcata.2013.03.007 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 5 февр. 2013 г. |
| Принята к публикации: | 12 мар. 2013 г. |
| Опубликована online: | 17 мар. 2013 г. |
| Опубликована в печати: | 1 июл. 2013 г. |
Идентификаторы БД:
| Web of science: | WOS:000319242800013 |
| Scopus: | 2-s2.0-84876900129 |
| РИНЦ: | 20441429 |
| Chemical Abstracts: | 2013:689568 |
| Chemical Abstracts (print): | 158:641300 |
| OpenAlex: | W1978077339 |