Application of the Site Blocking Method to the Investigation of the Kinetics of Carbon Monoxide Electrooxidation on Nanostructured Pt Full article
| Journal |
Journal of Solid State Electrochemistry
ISSN: 1432-8488 , E-ISSN: 1433-0768 |
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| Output data | Year: 2014, Volume: 18, Number: 5, Pages: 1195-1203 Pages count : 9 DOI: 10.1007/s10008-013-2251-8 | ||||||
| Tags | CO monolayer oxidation, Current transients, Electrocatalysis, Gold adatoms, Selective site blocking | ||||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | The Ministry of Education and Science of the Russian Federation | 8440 |
| 2 | Council for Grants of the President of the Russian Federation | НШ-524.2012.3 |
Abstract:
In this work, we apply a recently developed selective site blocking with gold adatoms (Kuznetsov et al. Electrocatal 3:211–220, 2012) for studying the electrooxidation of adsorbed carbon monoxide on electrodeposited Pt. The reaction is studied using chronoamperometry, and the obtained current transients are fitted with a nucleation-and-growth model in order to determine the characteristic kinetic parameters on defect and terrace (facet) sites. We conclude that Au selectively blocks defect sites up to very high coverages of 0.42 MLs, strongly slowing down the reaction kinetics. Blocking of defect sites with Au adatoms also results in an increase of the packing density of CO on terrace sites. The rate constant of CO oxidation on defects is higher than that on terraces and exhibits higher Tafel slope.
Cite:
Kuznetsov A.N.
, Parmon V.N.
, Savinova E.R.
Application of the Site Blocking Method to the Investigation of the Kinetics of Carbon Monoxide Electrooxidation on Nanostructured Pt
Journal of Solid State Electrochemistry. 2014. V.18. N5. P.1195-1203. DOI: 10.1007/s10008-013-2251-8 WOS Scopus РИНЦ OpenAlex ANCAN
Application of the Site Blocking Method to the Investigation of the Kinetics of Carbon Monoxide Electrooxidation on Nanostructured Pt
Journal of Solid State Electrochemistry. 2014. V.18. N5. P.1195-1203. DOI: 10.1007/s10008-013-2251-8 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Submitted: | Aug 13, 2013 |
| Accepted: | Sep 2, 2013 |
| Published online: | Oct 4, 2013 |
| Published print: | May 1, 2014 |
Identifiers:
| ≡ Web of science: | WOS:000336311400004 |
| ≡ Scopus: | 2-s2.0-84901471235 |
| ≡ Elibrary: | 22060088 |
| ≡ OpenAlex: | W2056427662 |
| ≡ Chemical Abstracts: | 2013:1567502 |
| ≡ Chemical Abstracts (print): | 160:644246 |
Citing:
| ≡ Scopus | Нет цитирований | Сбор данных от 15.02.2026 |
| ≡ Elibrary | Нет цитирований | Сбор данных от 08.02.2026 |
| ≡ OpenAlex | Нет цитирований | Сбор данных от 08.02.2026 |