Interaction of Molecular Nitrogen with the Alkali Metals. Communication 2. Activation of the N2 Molecule in Complexes of LinN2 | Sciact - CRIS-система Института катализа

Interaction of Molecular Nitrogen with the Alkali Metals. Communication 2. Activation of the N2 Molecule in Complexes of LinN2 Научная публикация

Журнал

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Вых. Данные

Год: 1976, Том: 25, Номер: 2, Страницы: 227-231 Страниц : 5 DOI: 10.1007/BF00922446

Ключевые слова

Nitrogen; Experimental Data; Electronic State; Alkali Metal; Molecular Nitrogen

Авторы

Avdeev V.I. ¹ , Zakharov I.I. ¹ , Borisov Yu.A. ² , Bulgakov N.N. ¹

Организации

1	Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk
2	Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

Conclusions: 1. In π-complexes LiNNn2, together with a stable electronic state, in which molecular nitrogen is in an inactivated form (K-state), stabilization of the electronic states in which the N-N bond is highly “loosened” (L-, M-states) is possible. 2. An analysis of the distribution of electron density in the complexes, for which L-, M-states are realized, together with the experimental data on the IR spectra, permitted us to conclude that the L- and M-states can be described as the result of one- or two-electron reduction of nitrogen in the complexes.

Avdeev V.I. , Zakharov I.I. , Borisov Y.A. , Bulgakov N.N.
Interaction of Molecular Nitrogen with the Alkali Metals. Communication 2. Activation of the N2 Molecule in Complexes of LinN2
Russian Chemical Bulletin. 1976. V.25. N2. P.227-231. DOI: 10.1007/BF00922446 WOS Scopus РИНЦ OpenAlex

Авдеев В.И. , Захаров И.И. , Борисов Ю.А. , Булгаков Н.Н.
Взаимодействие молекулярного азота с щелочными металлами. Сообщение 2. Активация молекулы N2 в комплексах LinN2
Известия Академии наук. Серия химическая. 1976. №2. С.239-244. РИНЦ CAPlusCA

Поступила в редакцию:	26 мар. 1975 г.
Опубликована в печати:	1 февр. 1976 г.

Web of science:	WOS:A1976CF63100001
Scopus:	2-s2.0-34250287805
РИНЦ:	30908183
OpenAlex:	W3015715476

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