Steady-Flow Investigation of the Kinetics of theReaction between V02+ and Phosphorus-Molybdenum-Vanadium Heteropoly Anions | Sciact - CRIS-system of Boreskov Institute of Catalysis

Steady-Flow Investigation of the Kinetics of theReaction between V02+ and Phosphorus-Molybdenum-Vanadium Heteropoly Anions Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 1980, Volume: 29, Number: 7, Pages: 1017-1021 Pages count : 5 DOI: 10.1007/BF00949145

Tags

Kinetic Equation; Intermediate Complex; Heteropoly Anion

Authors

Burov Yu.V. ¹ , Kozhevnikov I.V. ¹ , Matveev K.I. ¹ , Belyaev V.D. ¹

Affiliations

1	Institute of Catalysis, Siberian Branch of the Academy of Sciences of the USSR, Novosibirsk

Conclusions 1. It is found that the reaction of VO2+ with phosphorus-molybdenum-vanadium heteropoly anions (HPAN-n, n=0-6) at pH 2.2–3.0 obeys the kinetic equation v=k' [HPAN-n] [VO2+]/ [H+] α , whereαa=1.5 for HPAN-0 and 1.8 for HPAN-1, and that it includes the formation of an intraspherical intermediate complex [(HPAN-n), VO2+]. 2. The reactivity of HPAN-n varies in the following order: HPAN-0 > HPAN-1 > HPAN-2 < HPAN-3 < HPAN-4 < HPAN-5 < HPAN-6.

Burov Y.V. , Kozhevnikov I.V. , Matveev K.I. , Belyaev V.D.
Steady-Flow Investigation of the Kinetics of theReaction between V02+ and Phosphorus-Molybdenum-Vanadium Heteropoly Anions
Russian Chemical Bulletin. 1980. V.29. N7. P.1017-1021. DOI: 10.1007/BF00949145 WOS Scopus РИНЦ OpenAlex

Буров Ю.В. , Кожевников И.В. , Матвеев К.И. , Беляев В.Д.
Исследование кинетики взаимодействия VO2+ с фосформолибдованадиевыми гетерополианионами методом остановленной струи
Известия Академии наук. Серия химическая. 1980. №7. С.1469-1473. РИНЦ ANCAN

Submitted:	Jun 7, 1979
Published print:	Jul 1, 1980

Web of science:	WOS:A1980LG75100002
Scopus:	2-s2.0-34250238972
Elibrary:	30846212
OpenAlex:	W1976881507

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