Oxidation of Ethylene by Molecular-Oxygen in Presence of Pd(PPh3)4 | Sciact - CRIS-system of Boreskov Institute of Catalysis

Oxidation of Ethylene by Molecular-Oxygen in Presence of Pd(PPh3)4 ArticleGenre_short.LETTER

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 1977, Volume: 18, Number: 1, Pages: 210-211 Pages count : 2

Authors

Danilyuk A.F. ¹ , Likholobov V.A. ¹ , Ermakov Y.I. ¹

Affiliations

1	Institute of Catalysis, Siberian Branch of the USSR Academy of Sciences

MeCHO formation by the title reaction at 30° in dioxane containing aq. CF3CO2H was a 2nd-order process with rate const. 4.8 × 10-8 mol L-1 min-1. Ph3PO was also formed (rate const. 6.3 × 10-6) under these conditions, and added Co and LiH were converted to CO2 and LiOH, resp. A coordination mechanism was proposed.

Danilyuk A.F. , Likholobov V.A. , Ermakov Y.I.
Oxidation of Ethylene by Molecular-Oxygen in Presence of Pd(PPh3)4
Kinetics and Catalysis. 1977. V.18. N1. P.210-211. WOS РИНЦ

Данилюк А.Ф. , Лихолобов В.А. , Ермаков Ю.И.
Об окислении этилена молекулярным кислородом в присутствии Pd(PPh3)4
Кинетика и катализ. 1977. Т.18. №1. С.252-253. РИНЦ ANCAN

Submitted:

May 31, 1976

Web of science:	WOS:A1977EB64600023
Elibrary:	30626051

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