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Kinetics of Oxidation of Ethylene to Acetaldehyde by Phosphomolybdicvanadic Heteropolyacids in Presence of a Pd(II) Aquo Complex Full article

Journal Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Output data Year: 1977, Volume: 18, Number: 2, Pages: 320-326 Pages count : 7
Authors Matveev K.I. 1 , Zhizhina E.G. 1 , Shitova N.B. 1 , Kuznetsova L.I. 1
Affiliations
1 Institute of Catalysis, Siberian Branch of the USSR Academy of Sciences

Abstract: Kinetic data for the oxidation of C2H4 by H3+nPMo12-​nVnO40 (n = 0-​4) in the presence of PdSO4 indicated that the rate-​determining step was the oxidation of Pd(0)​-​C2H4 complexes. The Pd2+ existed as an aqua complex, and the heteropoly acid existed in equilibrium with vanadate and molybdate anions.
Cite: Matveev K.I. , Zhizhina E.G. , Shitova N.B. , Kuznetsova L.I.
Kinetics of Oxidation of Ethylene to Acetaldehyde by Phosphomolybdicvanadic Heteropolyacids in Presence of a Pd(II) Aquo Complex
Kinetics and Catalysis. 1977. V.18. N2. P.320-326. WOS РИНЦ
Original: Матвеев К.И. , Жижина Е.Г. , Шитова Н.Б. , Кузнецова Л.И.
Кинетика окисления этилена в ацетальдегид фосфорномолибденванадиевыми гетерополикислотами в присутствии аква-комплекса Pd(II)
Кинетика и катализ. 1977. Т.18. №2. С.380-386. РИНЦ ANCAN
Dates:
Submitted: Jan 9, 1976
Identifiers:
Web of science: WOS:A1977EC20200012
Elibrary: 28887616
Citing:
DB Citing
Web of science 20
Elibrary 6