Study of the Mechanism of Propagation and Transfer Reactions in the Polymerization of Olefins by Ziegler-Natta Catalysts, 4. The Kinetic Scheme for Propagation and Chain Transfer Reactions Full article
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Macromolecular Chemistry and Physics
ISSN: 1022-1352 , E-ISSN: 1521-3935 |
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| Output data | Year: 1977, Volume: 178, Number: 4, Pages: 967-980 Pages count : 14 DOI: 10.1002/macp.1977.021780404 | ||
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Abstract:
On the basis of the experimental data on the number of propagation centers, activation energy, and rate constants of propagation and transfer reactions, a kinetic scheme for propagation and chain transfer reactions in the polymerization of olefins in the presence of Ziegler-Natta catalysts is considered. The main features of this scheme are: a) monometallic composition of propagation centers; b) two-stage mechanism of the propagation reaction;
c) the reversible adsorption of an organoaluminium cocatalyst on the titanium ion of the propagation center resulting in its temporary deactivation and chain transfer with an organoaluminium compound.
Cite:
Zakharov V.A.
, Bukatov G.D.
, Chumaevskii N.B.
, Yermakov Y.I.
Study of the Mechanism of Propagation and Transfer Reactions in the Polymerization of Olefins by Ziegler-Natta Catalysts, 4. The Kinetic Scheme for Propagation and Chain Transfer Reactions
Macromolecular Chemistry and Physics. 1977. V.178. N4. P.967-980. DOI: 10.1002/macp.1977.021780404 WOS РИНЦ ANCAN OpenAlex
Study of the Mechanism of Propagation and Transfer Reactions in the Polymerization of Olefins by Ziegler-Natta Catalysts, 4. The Kinetic Scheme for Propagation and Chain Transfer Reactions
Macromolecular Chemistry and Physics. 1977. V.178. N4. P.967-980. DOI: 10.1002/macp.1977.021780404 WOS РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Jan 6, 1976 |
| Accepted: | Sep 16, 1976 |
| Published print: | Apr 1, 1977 |
| Published online: | Mar 12, 2003 |
Identifiers:
| Web of science: | WOS:A1977DB65600004 |
| Elibrary: | 29346950 |
| Chemical Abstracts: | 1977:190513 |
| Chemical Abstracts (print): | 86:190513 |
| OpenAlex: | W1512588799 |