Study of Copolymerization of Ethylene with Hex-1-ene on Applied Catalysts Full article
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Polymer Science U.S.S.R.
ISSN: 0032-3950 |
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| Output data | Year: 1980, Volume: 22, Number: 2, Pages: 448-454 Pages count : 7 DOI: 10.1016/0032-3950(80)90024-6 | ||
| Tags | CATALYSTS; POLYMERIZATION - Copolymerization | ||
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Abstract:
A study was made of copolymerization of ethylene with hex-1-ene on applied catalysts of various compositions which, according to activity at temperatures of 80–90° occupy the following order: Zr(C3H5)3Cl : SiO2 ⪡ CrO3 : SiO2−Al2O3 ⪡ TiCl4 : : MgCl2 + Al(C2H3)3. It was found that with low concentrations (up to 2–3 mole %) of hex-1-ene in the reaction mixture the rate of copolymerization is 2·5–3·0 times higher than in homopolymerization of ethylene on chromic oxide and titanium-magnesium catalysts. It was shown that other α-olefin monomers of linear structure have a similar effect on the rate of copolymerization with ethylene. The α-olefins examined occupy the following order, according to their effect on the rate of copolymerization with ethylene on a chromic oxide catalyst: 3-methylpent-1-ene<4-methylpent-1-ene<hept-1-ene<hex-1-ene<
pent-1-ene<propylene. The main properties of homo- and copolymers of ethylene were investigated.
Cite:
Finogenova L.T.
, Zakharov V.A.
, Buniyat-Zade A.A.
, Bukatov G.D.
, Plaksunov T.K.
Study of Copolymerization of Ethylene with Hex-1-ene on Applied Catalysts
Polymer Science U.S.S.R.. 1980. V.22. N2. P.448-454. DOI: 10.1016/0032-3950(80)90024-6 Scopus РИНЦ OpenAlex
Study of Copolymerization of Ethylene with Hex-1-ene on Applied Catalysts
Polymer Science U.S.S.R.. 1980. V.22. N2. P.448-454. DOI: 10.1016/0032-3950(80)90024-6 Scopus РИНЦ OpenAlex
Original:
Финогенова Л.Т.
, Захаров В.А.
, Бунят-Заде А.А.
, Букатов Г.Д.
, Плаксунов Т.К.
Исследование реакции сополимеризации этилена с гексеном-1 на нанесенных катализаторах
Высокомолекулярные соединения. Серия А. 1980. Т.22. №2. С.404-409. WOS РИНЦ ANCAN
Исследование реакции сополимеризации этилена с гексеном-1 на нанесенных катализаторах
Высокомолекулярные соединения. Серия А. 1980. Т.22. №2. С.404-409. WOS РИНЦ ANCAN
Dates:
| Submitted: | Dec 25, 1978 |
| Published print: | Feb 1, 1980 |
| Published online: | Jun 11, 2003 |
Identifiers:
| Scopus: | 2-s2.0-0019283746 |
| Elibrary: | 30956388 |
| OpenAlex: | W2050054753 |