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Proton Donor Ability of Surface Hydroxy Groups from the IR Spectra of Hydrogen-Bonded Complexes Full article

Journal Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837
Output data Year: 1978, Volume: 9, Number: 3, Pages: 265-268 Pages count : 4 DOI: 10.1007/BF02070497
Tags Phosphate; Physical Chemistry; Zeolite; Catalysis; Frequency Shift
Authors Paukshtis E.A. 1 , Karakchiev L.G. 1 , Kotsarenko N.S. 1
Affiliations
1 Institute of Catalysis, Novosibirsk, USSR

Abstract: The influence of the strength of N-bases on the shift of ν (OH) in hydrogen-bonded complexes upon adsorption on the surface of a decationized zeolite, phosphates and aerosil differing in the proton donor ability of surface hydroxy groups has been investigated. It is shown that the acid-base properties of the adsorbent-adsorbate pair produce additive influence on the above frequency shifts. A method for the determination of the proton donor ability of surface hydroxy groups (in terms of pKa) from the IR spectra of hydrogen-bonded complexes is suggested.
Cite: Paukshtis E.A. , Karakchiev L.G. , Kotsarenko N.S.
Proton Donor Ability of Surface Hydroxy Groups from the IR Spectra of Hydrogen-Bonded Complexes
Reaction Kinetics and Catalysis Letters. 1978. V.9. N3. P.265-268. DOI: 10.1007/BF02070497 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Jan 2, 1978
Accepted: Apr 14, 1978
Published print: Sep 1, 1978
Identifiers:
Web of science: WOS:A1978GE79400004
Scopus: 2-s2.0-34250281026
Elibrary: 30919949
Chemical Abstracts: 1979:93051
Chemical Abstracts (print): 90:93051
OpenAlex: W2009577070
Citing:
DB Citing
Web of science 9
Scopus 7
Elibrary 8
OpenAlex 6
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