Nanosized Co-Ni/Glass Fiber Catalysts Prepared by “Solution-Combustion” Method | Sciact - CRIS-system of Boreskov Institute of Catalysis

Nanosized Co-Ni/Glass Fiber Catalysts Prepared by “Solution-Combustion” Method Full article

Journal

Journal of Nanoscience and Nanotechnology
ISSN: 1533-4880 , E-ISSN: 1533-4899

Output data

Year: 2013, Volume: 3, Number: 1, Pages: 1-9 Pages count : 9 DOI: 10.5923/j.nn.20130301.01

Tags

Dry Reforming of Methane, CO Oxidation, Butane Oxidation, Co-Ni-Catalyst, Glass Fiber Catalyst, Self-Propagating High Temperature Synthesis

Authors

Ismagilov Z.R. ^1,2 , Mansurov Z.A. ³ , Shikina N.V. ¹ , Yashnik S.A. ¹ , Aldashukurova G.B. ³ , Mironenko A.V. ³ , Kuznetsov V.V. ¹ , Ismagilov I.Z. ¹

Affiliations

1	Boreskov Institute of Catalysis of SB RAS, Novosibirsk, 630090, Russia
2	Institute of Coal Chemistry and Material Science of SB RAS, Kemerovo, 650000, Russia
3	Institute for Problems in Combustion, Almaty, 050012, Kazakhstan

Nanostructured low percent Co-Ni catalysts on the basis of glass fibers (GF) were synthesized by a “solution combustion” (SC) method. Catalytic activity of prepared samples was studied in the reaction of dry reforming of methane (DRM) with СО2, CO and butane oxidation reactions. Physico-chemical characteristics of obtained species were studied by XRD, TEM, TGA, AFM, H2-TPR and DR UV-Vis. The active component was shown to be dispersed in the near-surface layer of the support as nanoparticles of size 10–20 nm, which have a Co3O4 or (Co,Ni)Co2O4 spinel structure depending on the catalyst composition. The spinel structure of the active component strongly interacting with the carrier is resistant to carbonization and provides high catalytic activity in DRM, and high activity and stability in oxidation reactions.

Ismagilov Z.R. , Mansurov Z.A. , Shikina N.V. , Yashnik S.A. , Aldashukurova G.B. , Mironenko A.V. , Kuznetsov V.V. , Ismagilov I.Z.
Nanosized Co-Ni/Glass Fiber Catalysts Prepared by “Solution-Combustion” Method
Journal of Nanoscience and Nanotechnology. 2013. V.3. N1. P.1-9. DOI: 10.5923/j.nn.20130301.01 РИНЦ ANCAN

Elibrary:	23628333
Chemical Abstracts:	2014:483096
Chemical Abstracts (print):	161:218437

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