Determination of the Rate Constants for Chain Transfer with the Monomer and Hydrogen in Ziegler-Natta Polymerization Научная публикация
| Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Вых. Данные | Год: 1976, Том: 5, Номер: 4, Страницы: 429-434 Страниц : 6 DOI: 10.1007/BF02060890 | ||
| Ключевые слова | Hydrogen; Polymerization; Ethylene; Physical Chemistry; Catalysis | ||
| Авторы |
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| Организации |
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Реферат:
The rate constants of chain transfer with the monomer and hydrogen in the polymerization of ethylene and propylene by the catalyst δ-TiCl3, 0.3 AlCl3 + Al(C2H5)3 have been determined. For chain transfer with ethylene and propylene these values are equal to 0.84 l/mol-1 sec-1 (80 °C) and 0.04 lmol-1 sec-1 (70°C), respectively, and: for chain transfer with hydrogen they amount to 23 l 1/2mol-1/2 sec-1 (ethylene polymerization, 80 °C) and 6 l1/2 mol -1/2 sec (propylene polymerization, 70°C).
Библиографическая ссылка:
Zakharov V.A.
, Chumaevskii N.B.
, Bulatova Z.K.
, Bukatov G.D.
, Yermakov Y.I.
Determination of the Rate Constants for Chain Transfer with the Monomer and Hydrogen in Ziegler-Natta Polymerization
Reaction Kinetics and Catalysis Letters. 1976. V.5. N4. P.429-434. DOI: 10.1007/BF02060890 WOS Scopus РИНЦ CAPlusCA OpenAlex
Determination of the Rate Constants for Chain Transfer with the Monomer and Hydrogen in Ziegler-Natta Polymerization
Reaction Kinetics and Catalysis Letters. 1976. V.5. N4. P.429-434. DOI: 10.1007/BF02060890 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 27 мая 1976 г. |
| Принята к публикации: | 13 июл. 1976 г. |
| Опубликована в печати: | 1 дек. 1976 г. |
Идентификаторы БД:
| Web of science: | WOS:A1976CR21800008 |
| Scopus: | 2-s2.0-0006448839 |
| РИНЦ: | 30802356 |
| Chemical Abstracts: | 1977:73203 |
| Chemical Abstracts (print): | 86:73203 |
| OpenAlex: | W2076989430 |