Determination of the Number of Active Centres and Growth Rate Constants in the Catalytic Polymerisation of α-Alkenes | Sciact - CRIS-система Института катализа

Determination of the Number of Active Centres and Growth Rate Constants in the Catalytic Polymerisation of α-Alkenes Обзор

Журнал

Russian Chemical Reviews
ISSN: 0036-021X , E-ISSN: 1468-4837

Вых. Данные

Год: 1972, Том: 41, Номер: 3, Страницы: 203-215 Страниц : 13 DOI: 10.1070/RC1972v041n03ABEH002039

Авторы

Ermakov Y.I. ¹ , Zakharov V.A. ¹

Организации

1	Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk

The reliability of different methods for determining the number of active centres (n) and calculating the growth rate constants (kg) in the catalytic polymerisation of α-alkenes is discussed. The values of n and kg obtained for different catalytic systems are given. Information on the dependence of the number of growth centres and the rate constants of the separate steps (primarily the growth rate constants) on the composition of the catalyst, its method of preparation, and the conditions of polymerisation can yield important conclusions regarding the mechanism of polymerisation and the composition of the active centres.

Ermakov Y.I. , Zakharov V.A.
Determination of the Number of Active Centres and Growth Rate Constants in the Catalytic Polymerisation of α-Alkenes
Russian Chemical Reviews. 1972. V.41. N3. P.203-215. DOI: 10.1070/RC1972v041n03ABEH002039 Scopus РИНЦ OpenAlex

Ермаков Ю.И. , Захаров В.А.
Определение числа активных центров и константы скорости роста при каталитической полимеризации-олефинов
Успехи химии. 1972. Т.41. №3. С.377-400. WOS РИНЦ CAPlusCA

Опубликована в печати:	31 мар. 1972 г.
Опубликована online:	17 окт. 2007 г.

Scopus:	2-s2.0-84916081343
РИНЦ:	32801715
OpenAlex:	W2049393086

БД	Цитирований
Scopus	7
РИНЦ	6
OpenAlex	15