The First Example of Ortho-Directing Effect of Weakly Coordinating Substituent [-BF3–] in the Catalytic Hydrodefluorination Reaction of Pentafluorophenyltrifluoroborate Anion | Sciact - CRIS-system of Boreskov Institute of Catalysis

The First Example of Ortho-Directing Effect of Weakly Coordinating Substituent [-BF3–] in the Catalytic Hydrodefluorination Reaction of Pentafluorophenyltrifluoroborate Anion Full article

Journal

Mendeleev Communications
ISSN: 0959-9436 , E-ISSN: 1364-551X

Output data

Year: 2009, Volume: 19, Number: 5, Pages: 260-262 Pages count : 3 DOI: 10.1016/j.mencom.2009.09.009

Tags

C-F BOND; CARBON FLUORINE BONDS; CRYSTAL-STRUCTURE; CYCLOMETALLATION REACTIONS; INTRAMOLECULAR ACTIVATION; PHOSPHINE COMPLEXES; NICKEL-COMPLEXES; METAL-COMPLEXES; LEWIS-ACIDS; H BONDS

Authors

Adonin Nicolay Yu. ¹ , Prikhodko Sergey A. ¹ , Bardin Vadim V. ² , Parmon Valentin N. ¹

Affiliations

1	G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation
2	N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation

The pentafluorophenyltrifluoroborate anion undergoes hydrodefluorination under the action of zinc in the presence of nickel complexes turning into the 2,3,4,5-tetrafluoroborate anion.

Adonin N.Y. , Prikhodko S.A. , Bardin V.V. , Parmon V.N.
The First Example of Ortho-Directing Effect of Weakly Coordinating Substituent [-BF3–] in the Catalytic Hydrodefluorination Reaction of Pentafluorophenyltrifluoroborate Anion
Mendeleev Communications. 2009. V.19. N5. P.260-262. DOI: 10.1016/j.mencom.2009.09.009 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Mar 20, 2009
Published print:	Sep 1, 2009
Published online:	Sep 26, 2009

Web of science:	WOS:000271368800009
Scopus:	2-s2.0-70349313253
Elibrary:	15307722
Chemical Abstracts:	2009:1371600
Chemical Abstracts (print):	152:501426
OpenAlex:	W2058293916

DB	Citing
Web of science	14
Scopus	15
Elibrary	14
OpenAlex	16