Sciact
  • EN
  • RU

Catalytic Detoxification of 1,1-Dimethylhydrazine Aqueous Solutions in Heterogeneous Fenton System Full article

Journal Applied Catalysis B: Environmental
ISSN: 0926-3373 , E-ISSN: 1873-3883
Output data Year: 2006, Volume: 68, Number: 3-4, Pages: 85-91 Pages count : 7 DOI: 10.1016/j.apcatb.2006.07.008
Tags FeZSM-5, Heterogeneous Fenton, Hydrogen peroxide, N-Nitrosodimethylamine, UDMH, Unsymmetrical dimethylhydrazine
Authors Makhotkina O.A. 1 , Kuznetsova E.V. 2 , Preis S.V. 3
Affiliations
1 Novosibirsk State University, Pirogov Str. 2, Novosibirsk 630090, Russia
2 Boreskov Institute of Catalysis, Ak. Lavrentiev Ave. 5, Novosibirsk 630090, Russia
3 Lappeenranta University of Technology, Skinnarilankatu 34, Lappeenranta 53850, Finland

Funding (2)

1 North Atlantic Treaty Organization SfP-981461
2 Academy of Finland 208134

Abstract: The experimental study into catalytic properties of FeZSM-5 was undertaken into oxidation of 1,1-dimethylhydrazine (UDMH) aqueous solutions using hydrogen peroxide. The performances of heterogeneous and homogeneous Fenton systems were compared. UDMH complete mineralization was achieved. Formic and acetic acids, as well as nitromethane, were identified as oxidation by-products. Adsorption properties of FeZSM-5 with respect to hydrogen peroxide, 1,1-dimethylhydrazine and N-nitrosodimethylamine have been studied. The effects of the oxidant and the target compound concentrations, temperature and pH of aqueous solution were established.
Cite: Makhotkina O.A. , Kuznetsova E.V. , Preis S.V.
Catalytic Detoxification of 1,1-Dimethylhydrazine Aqueous Solutions in Heterogeneous Fenton System
Applied Catalysis B: Environmental. 2006. V.68. N3-4. P.85-91. DOI: 10.1016/j.apcatb.2006.07.008 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Mar 13, 2006
Accepted: Jul 12, 2006
Published online: Aug 28, 2006
Published print: Nov 7, 2006
Identifiers:
Web of science: WOS:000241707700001
Scopus: 2-s2.0-33749620370
Elibrary: 13524001
Chemical Abstracts: 2006:1076168
Chemical Abstracts (print): 145:459503
OpenAlex: W2082134170
Citing:
DB Citing
Web of science 65
Scopus 71
Elibrary 73
OpenAlex 73
Altmetrics: