Effect of Oxygen Mobility in Solid Catalyst on Transient Regimes of Catalytic Reaction of Methane Partial Oxidation at Short Contact Times Full article
| Journal |
Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X |
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| Output data | Year: 2006, Volume: 110, Number: 3-4, Pages: 235-242 Pages count : 8 DOI: 10.1007/s10562-006-0114-y | ||
| Tags | Methane partial oxidation, Oxygen mobility, Transient regimes | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Foundation for Basic Research | 05-03-34761 |
Abstract:
Mathematical modeling of the effect of the oxygen mobility in a solid oxide catalyst on the dynamics of transients of fast catalytic reactions has been carried out. The analysis was based upon the redox mechanistic scheme with a due regard for diffusion of oxygen from the bulk of catalyst to its surface. Parameters of kinetic and mathematical models were selected via fitting of the experimental data for methane selective oxidation into syngas on 1.4%Pt/Gd0.2Ce0.4Zr0.4Ox catalyst. The range of the Thiele parameter (φ) where the oxygen bulk diffusion affects the most strongly reaction transients corresponds to φε [0.3 ÷ 7]. For high-surface-area oxide catalysts, the bulk oxygen diffusion coefficients corresponding to this range of the Thiele parameter are in the range of 10–18 ÷ 10–13cm2/s.
Cite:
Reshetnikov S.I.
, Lukashevich A.I.
, Alikina G.M.
, Sadykov V.A.
Effect of Oxygen Mobility in Solid Catalyst on Transient Regimes of Catalytic Reaction of Methane Partial Oxidation at Short Contact Times
Catalysis Letters. 2006. V.110. N3-4. P.235-242. DOI: 10.1007/s10562-006-0114-y WOS Scopus РИНЦ ANCAN OpenAlex
Effect of Oxygen Mobility in Solid Catalyst on Transient Regimes of Catalytic Reaction of Methane Partial Oxidation at Short Contact Times
Catalysis Letters. 2006. V.110. N3-4. P.235-242. DOI: 10.1007/s10562-006-0114-y WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | May 1, 2006 |
| Accepted: | Jun 11, 2006 |
| Published print: | Sep 1, 2006 |
Identifiers:
| Web of science: | WOS:000239813800010 |
| Scopus: | 2-s2.0-33747437666 |
| Elibrary: | 13519365 |
| Chemical Abstracts: | 2006:831009 |
| Chemical Abstracts (print): | 145:422008 |
| OpenAlex: | W1976229939 |