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Effect of Complex Oxide Promoters and Pd on Activity and Stability of Ni/YSZ (ScSZ) Cermets as Anode Materials for IT SOFC Научная публикация

Конференция 4th Asia-Pacific Congress on Catalysis
06-08 дек. 2006 , Singapore
Журнал Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308
Вых. Данные Год: 2008, Том: 131, Номер: 1-4, Страницы: 226-237 Страниц : 12 DOI: 10.1016/j.cattod.2007.10.064
Ключевые слова EDX, H2 and CH4 TPR, Methane steam reforming, Microstructure, Promoters, SOFC composite anodes, TEM
Авторы Sadykov Vladislav A. 1 , Mezentseva Natalia V. 1 , Bunina Rimma V. 1 , Alikina Galina M. 1 , Lukashevich Anton I. 1 , Kharlamova Tamara S. 1 , Rogov Vladimir A. 1 , Zaikovskii Vladimir I. 1 , Ishchenko Arcady V. 1 , Krieger Tamara A. 1 , Bobrenok Oleg F. 2 , Smirnova Alevtina 3 , Irvine John 4 , Vasylyev Oleksandr D. 5
Организации
1 Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russian Federation
2 Institute of Thermophysics SB RAS, Novosibirsk, Russian Federation
3 Global Fuel Cells Center, University of Connecticut, Storrs, CT, USA
4 School of Chemistry, University of St. Andrews, Fife, United Kingdom
5 Institute for Problems of Materials Science, Kiev, Ukraine

Информация о финансировании (2)

1 Сибирское отделение Российской академии наук 95
2 North Atlantic Treaty Organization SfP-980878

Реферат: Effect of fluorite-like or perovskite-like complex oxide promoters, Pd and Cu on the performance of Ni/8YSZ and Ni/ScCeSZ anode materials in CH4 steam reforming (SR) or selective oxidation (SO) by O2 into syngas was studied. The spatial distribution of dopants in composites before and after contact with the reaction feed, features of components mutual interaction and forms of deposited coke were controlled by TEM combined with EDX analysis. The lattice oxygen mobility and reactivity were estimated by CH4 and H2 temperature-programmed reduction (TPR), and the amount of deposited carbon after operation in the feed with stoichiometric H2O/CH4 ratio was estimated by the temperature-programmed oxidation. Promoters decrease the amount of deposited coke, while doping by Pd or Cu ensures also a good and stable performance at moderate (550 8C) temperatures required for the intermediate-temperature solid oxide fuel cells (IT SOFC) operation.
Библиографическая ссылка: Sadykov V.A. , Mezentseva N.V. , Bunina R.V. , Alikina G.M. , Lukashevich A.I. , Kharlamova T.S. , Rogov V.A. , Zaikovskii V.I. , Ishchenko A.V. , Krieger T.A. , Bobrenok O.F. , Smirnova A. , Irvine J. , Vasylyev O.D.
Effect of Complex Oxide Promoters and Pd on Activity and Stability of Ni/YSZ (ScSZ) Cermets as Anode Materials for IT SOFC
Catalysis Today. 2008. V.131. N1-4. P.226-237. DOI: 10.1016/j.cattod.2007.10.064 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Опубликована online: 26 нояб. 2007 г.
Опубликована в печати: 29 февр. 2008 г.
Идентификаторы БД:
Web of science: WOS:000253382100032
Scopus: 2-s2.0-38349164811
РИНЦ: 13571062
Chemical Abstracts: 2008:109036
Chemical Abstracts (print): 148:406232
OpenAlex: W2056577817
Цитирование в БД:
БД Цитирований
Web of science 17
Scopus 25
РИНЦ 24
OpenAlex 22
Альметрики: