Development of Catalysts for Hydrogen Generation from Hydride Compounds | Sciact - CRIS-system of Boreskov Institute of Catalysis

Development of Catalysts for Hydrogen Generation from Hydride Compounds Full article

Conference

8th European Workshop Meeting on Selective Oxidation
26-31 Aug 2007 , Turku

Journal

Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308

Output data

Year: 2008, Volume: 138, Number: 3-4, Pages: 253-259 Pages count : 7 DOI: 10.1016/j.cattod.2008.05.022

Tags

Ammonia borane, Catalyst, Hydrogen generation, Hydrolysis, Sodium borohydride

Authors

Simagina Valentina I. ¹ , Storozhenko Pavel A. ² , Netskina Olga V. ¹ , Komova Oksana V. ¹ , Odegova Galina V. ¹ , Larichev Yury V. ¹ , Ishchenko Arcady V. ¹ , Ozerova Anna M. ^1,3

Affiliations

1	Boreskov Institute of Catalysis SB RAS, Pr. Akademika Lavrentieva 5, Novosibirsk 630090, Russia
2	State Research Institute of Chemistry and Technology of Organoelement Compounds, Sh. Entuziastov 38, Moscow 111123, Russia
3	Novosibirsk State University, Pirogova street, 2, Novosibirsk 630090, Russia

Catalytic hydrolysis of NaBH4 and NH3BH3 has been studied. It was shown that the nature of the support and the active component of the catalyst affect the H2 generation rate. Despite similar sizes of rhodium particles formed on the surface of different supports (g-Al2O3, TiO2, carbon), their reactivity is different. Rh/TiO2 with low rhodium concentration (1 wt.%) is the most active catalyst both in the hydrolysis of NaBH4 and NH3BH3. The obtained results show that the rhodium chloride interaction with titania determines the reactivity of rhodium particles formed under action of NaBH4 medium. TEM, DRS UV–vis and XPS were used to characterize the catalysts.

Simagina V.I. , Storozhenko P.A. , Netskina O.V. , Komova O.V. , Odegova G.V. , Larichev Y.V. , Ishchenko A.V. , Ozerova A.M.
Development of Catalysts for Hydrogen Generation from Hydride Compounds
Catalysis Today. 2008. V.138. N3-4. P.253-259. DOI: 10.1016/j.cattod.2008.05.022 WOS Scopus РИНЦ ANCAN OpenAlex

Published online:	Jul 7, 2008
Published print:	Nov 1, 2008

Web of science:	WOS:000261098800025
Scopus:	2-s2.0-53449098386
Elibrary:	13591619
Chemical Abstracts:	2008:1277334
Chemical Abstracts (print):	150:38056
OpenAlex:	W2065445355

DB	Citing
Web of science	61
Scopus	66
Elibrary	64
OpenAlex	64