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Calculation of Phase Diagrams of Heterophase Two- and Three-Component Liquid Mixtures 'α-Pinene-Water' and 'α-Pinene-Water-Ethanol' Научная публикация

Журнал Chemical Engineering Science
ISSN: 0009-2509 , E-ISSN: 1873-4405
Вых. Данные Год: 2008, Том: 63, Номер: 24, Страницы: 5854-5859 Страниц : 6 DOI: 10.1016/j.ces.2008.08.020
Ключевые слова 'α-Pinene-water' and 'α-pinene-ethanol-water', Critical curve, Heteroazeotropic state, Phase behavior, Supercritical conditions, Thermodynamic, Two- and three-component mixtures
Авторы Yermakova A. 1 , Chibiryaev A.M. 2 , Kozhevnikov I.V. 1 , Anikeev V.I. 1
Организации
1 Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, pr. Akad. Lavrentieva, 5, 630090 Novosibirsk, Russian Federation
2 Vorozhtsov Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, pr. Akad. Lavrentieva, 9, 630090 Novosibirsk, Russian Federation

Информация о финансировании (2)

1 Российский фонд фундаментальных исследований 06-08-00024
2 Российский фонд фундаментальных исследований 05-08-65437

Реферат: Phase behaviors of two- and three-component mixtures `-pinene–water' and `-pinene–ethanol–water' were studied over a wide range of their composition, temperature, and pressure. Conditions were found that provide heteroazeotropic states of binary mixture `-pinene–water' and ternary mixture `-pinene–ethanol–water' depending on the ratio of `water/(-pinene+ethanol)' fractions at the `- pinene+ethanol' ratio of 1:1. Critical curves were calculated to demonstrate an anomalous dependence of these curves on the mixture composition, with the temperature minimum points typical of the mixtures that form heteroazeotropes.
Библиографическая ссылка: Yermakova A. , Chibiryaev A.M. , Kozhevnikov I.V. , Anikeev V.I.
Calculation of Phase Diagrams of Heterophase Two- and Three-Component Liquid Mixtures 'α-Pinene-Water' and 'α-Pinene-Water-Ethanol'
Chemical Engineering Science. 2008. V.63. N24. P.5854-5859. DOI: 10.1016/j.ces.2008.08.020 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 30 окт. 2007 г.
Принята к публикации: 22 авг. 2008 г.
Опубликована online: 2 сент. 2008 г.
Опубликована в печати: 1 дек. 2008 г.
Идентификаторы БД:
Web of science: WOS:000261363300009
Scopus: 2-s2.0-55049096776
РИНЦ: 13597244
Chemical Abstracts: 2008:1348918
Chemical Abstracts (print): 149:583252
OpenAlex: W2060801387
Цитирование в БД:
БД Цитирований
Web of science 1
Scopus 1
РИНЦ 1
OpenAlex 1
Альметрики: