Реферат: A review. As early as in 1990s, a new era in the development of porous solid materials commenced with the appearance of a novel class of porous solid materials - zeolite analogs - constituted by isolated metal ions interconnected by polytopic org. ligands into multidimensional structures. In 2000s, the area of the metal-​org. frameworks (MOFs) expanded greatly, due to the low cost, the versatility of the org. ligands chem. and coordination chem. of metal ions. The structures of the resulting porous MOFs featured void vols. of variable size and topologies and metal centers accessible by guest mols. that suggested such applications as selective sorption, gas storage, sensing and sepn., ion exchange and catalysis. The efforts to incorporate enantiomerically pure homochiral building blocks into microporous materials, in turn, created potential opportunities for enantiomeric recognition, sorption and sepn., and asym. catalysis. So far, examples of successful stereoselective recognition and catalysis by MOFs are rather scarce, but this no. is continuously increasing, and, taking into account the importance of chirality in living nature, the authors foresee a rapid development of new homochiral metal-​org. frameworks capable of such applications in near future. In this commentary, the authors present an overview of known homochiral metal-​org. materials capable of stereoselective recognition, sorption and sepn. of guest mols. and those promoting asym. catalytic processes inside the chiral pores.

Библиографическая ссылка: Brylyakov K.P. , Talsi E.P.
Homochiral Porous Metal-Organic Frameworks: A Step to the Future of Stereoselective Recognition and Catalysis
В сборнике Transition Metal Chemistry: New Research. 2008. – C.47-59. – ISBN 978-160456702-1. Scopus РИНЦ РИНЦ CAPlusCA

Идентификаторы БД:

Scopus:	2-s2.0-77956443263
РИНЦ:	20140081 | 21907507
Chemical Abstracts:	2010:320027
Chemical Abstracts (print):	154:181710

Цитирование в БД:

БД	Цитирований
Scopus	3
РИНЦ	3