Titanium-Salan-Catalyzed Asymmetric Oxidation of Sulfides and Kinetic Resolution of Sulfoxides with H2O2 as the Oxidant Full article
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European Journal of Organic Chemistry
ISSN: 1434-193X , E-ISSN: 1099-0690 |
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| Output data | Year: 2008, Number: 19, Pages: 3369-3376 Pages count : 8 DOI: 10.1002/ejoc.200800277 | ||
| Tags | Asymmetric catalysis, Hydrogen peroxide, Kinetic resolution, Oxidation, Sulfoxides, Titanium | ||
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Abstract:
Asymmetric oxidation of sufides to sulfoxides by aqueous hydrogen peroxide with catalysis by titanium-salan complexes is presented. Optically active sulfoxides have been obtained with good to high enantioselectivities (up to 97 % ee) by a tandem enantioselective oxidation and kinetic resolution procedure, the catalyst performing over 500 turnovers with no loss of enantioselectivity.
Cite:
Bryliakov K.P.
, Talsi E.P.
Titanium-Salan-Catalyzed Asymmetric Oxidation of Sulfides and Kinetic Resolution of Sulfoxides with H2O2 as the Oxidant
European Journal of Organic Chemistry. 2008. N19. P.3369-3376. DOI: 10.1002/ejoc.200800277 WOS Scopus РИНЦ ANCAN OpenAlex
Titanium-Salan-Catalyzed Asymmetric Oxidation of Sulfides and Kinetic Resolution of Sulfoxides with H2O2 as the Oxidant
European Journal of Organic Chemistry. 2008. N19. P.3369-3376. DOI: 10.1002/ejoc.200800277 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Mar 13, 2008 |
| Published online: | May 9, 2008 |
| Published print: | Jul 1, 2008 |
Identifiers:
| Web of science: | WOS:000257528900017 |
| Scopus: | 2-s2.0-53749088041 |
| Elibrary: | 13574232 |
| Chemical Abstracts: | 2008:862309 |
| Chemical Abstracts (print): | 149:223725 |
| OpenAlex: | W1971116155 |