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The Thermal Stability of Nanodiamond Surface Groups and Onset of Nanodiamond Graphitization Full article

Conference 7th Biennial International Workshop on Fullerenes and Atomic Clusters
27 Jun - 1 Jul 2005 , St. Petersburg
Journal Fullerenes Nanotubes and Carbon Nanostructures
ISSN: 1536-383X , E-ISSN: 1536-4046
Output data Year: 2006, Volume: 14, Number: 2-3, Pages: 557-564 Pages count : 8 DOI: 10.1080/15363830600666779
Tags Graphitization, Nanodiamond, Surface groups
Authors Butenko Yu.V. 1 , Kuznetsov V.L. 1 , Paukshtis E.A. 1 , Stadnichenko A.I. 1 , Mazov I.N. 1 , Moseenkov S.I. 1 , Boronin A.I. 1 , Kosheev S.V. 1
Affiliations
1 Boreskov Institute of Catalysis, Novosibirsk, Russian Federation

Funding (3)

1 Russian Foundation for Basic Research 05-03-32995
2 North Atlantic Treaty Organization SFP-981051
3 Civilian Research and Development Foundation NO-008-X1

Abstract: The results of study of the surface chemistry of nanodiamonds treated by a mixture of HClO4 and H2SO2 acids are presented. Changes of the composition of surface diamond groups brought up by thermal annealing were monitored by Fourier transformed infrared spectroscopy and temperature‐programmed desorption. The decomposition of oxygen‐containing groups is observed at 300–900°C; CHx groups decompose at 700–1150°C. The process of the annealing of ND was investigated by the X‐ray photoelectron spectroscopy. The clear onset of ND graphitization was observed at temperature of 950°C that is supported by the appearance of sp 2 component in the C1s spectrum. The presence of the N1s peak in spectra of ND is observed in initial and partially graphitized ND annealed up to 1100°C.
Cite: Butenko Y.V. , Kuznetsov V.L. , Paukshtis E.A. , Stadnichenko A.I. , Mazov I.N. , Moseenkov S.I. , Boronin A.I. , Kosheev S.V.
The Thermal Stability of Nanodiamond Surface Groups and Onset of Nanodiamond Graphitization
Fullerenes Nanotubes and Carbon Nanostructures. 2006. V.14. N2-3. P.557-564. DOI: 10.1080/15363830600666779 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Published print: Apr 1, 2006
Published online: Aug 22, 2006
Identifiers:
Web of science: WOS:000238762900064
Scopus: 2-s2.0-33745122200
Elibrary: 13513485
Chemical Abstracts: 2006:682482
Chemical Abstracts (print): 146:303157
OpenAlex: W1987486433
Citing:
DB Citing
Web of science 68
Scopus 74
Elibrary 71
OpenAlex 75
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