Porous Substrates for Intermediate Temperature SOFCs and In-Cell Reforming Catalysts | Sciact - CRIS-система Института катализа

Porous Substrates for Intermediate Temperature SOFCs and In-Cell Reforming Catalysts Обзор

Журнал

Catalysis for Sustainable Energy
ISSN: 2084-6819

Вых. Данные

Год: 2013, Том: 1, Страницы: 90-99 Страниц : 10 DOI: 10.2478/cse-2013-0005

Ключевые слова

SOFC substrate • Porous • Graded design • Composite structure

Авторы

Smorygo Oleg ¹ , Sadykov Vladislav ² , Mikutski Vitali ¹ , Marukovich Alexander ¹ , Ilyushchanka Aliaksandr ¹ , Yarkovich Alexander ¹ , Mezentseva Natalia ² , Bobrova Ludmila ² , Fedorova Yulia ² , Pelipenko Vladimir ² , Arapova Marina ² , Smirnova Alevtina ³

Организации

1	Department of Porous Materials, Powder Metallurgy Institute, 41, Platonov str., Minsk 220005, Belarus
2	Laboratory of Deep Oxidation Catalysts, Boreskov Institute of Catalysis, 5, Lavrentiev Ave., Novosibirsk 63009, Russia
3	Chemistry Department, South Dakota, School of Mines and Technology, 501 E. St Joseph str., Rapid City, SD 57701, USA

Информация о финансировании (4)

1	Российский фонд фундаментальных исследований	12-03-93115
2	Национальная академия наук Беларуси	T09CO-003
3	Белорусский республиканский фонд фундаментальных исследований Сибирское отделение Российской академии наук	T12CO-020
4	Сибирское отделение Российской академии наук	8

The paper reviews results of development of new composite foam substrates with the graded structure for the intermediate temperature SOFC and structured catalysts of fuels reforming. Ni-Al substrates with porosity of 60-80% were prepared by compressive deformation of open cell metal foams followed by pack aluminizing. Testing in corrosive media revealed advantages of Ni-Al substrates over Fechraloy ones. Button-size thin film solid oxide fuel cell supported on this substrate demonstrated promising performance in the intermediate temperature range. These substrates were shown to be compatible with nanocomposite active components for the fuel reforming comprised of Ni-based alloys strongly interacting with perovskite/fluorite complex oxides with a high oxygen mobility and reactivity. High activity and coking stability of these structured catalysts in steam/autothermal reforming of natural gas, ethanol and acetone was demonstrated without a remarkable impact of heat and mass transfer. A close performance was demonstrated for fuel cells operating on wet H2 or in the mode of internal reforming of natural gas using these catalysts. A concept of the substrate with the graded pore structure and composition was offered.

Smorygo O. , Sadykov V. , Mikutski V. , Marukovich A. , Ilyushchanka A. , Yarkovich A. , Mezentseva N. , Bobrova L. , Fedorova Y. , Pelipenko V. , Arapova M. , Smirnova A.
Porous Substrates for Intermediate Temperature SOFCs and In-Cell Reforming Catalysts

Catalysis for Sustainable Energy. 2013. V.1. P.90-99. DOI: 10.2478/cse-2013-0005 РИНЦ CAPlusCA OpenAlex

Полный текст от издателя

Опубликована в печати:	24 янв. 2013 г.
Поступила в редакцию:	19 мар. 2013 г.
Принята к публикации:	13 мая 2013 г.
Опубликована online:	24 мая 2013 г.

РИНЦ:	21469976
Chemical Abstracts:	2015:611957
Chemical Abstracts (print):	163:106377
OpenAlex:	W1834924562

БД	Цитирований
РИНЦ	9
OpenAlex	6