Methane Carbonylation with CO on Sulfated Zirconia: Evidence from Solid-State NMR for the Selective Formation of Acetic Acid Научная публикация
| Журнал |
The Journal of Physical Chemistry C
ISSN: 1932-7447 , E-ISSN: 1932-7455 |
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| Вых. Данные | Год: 2007, Том: 111, Номер: 28, Страницы: 10624-10629 Страниц : 6 DOI: 10.1021/jp0728757 | ||
| Ключевые слова | Acetic acid; Carbonylation; Nuclear magnetic resonance spectroscopy; Solid state reactions; Sulfonation; Zirconia | ||
| Авторы |
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| Организации |
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Реферат:
Using 13C and 1H solid-state NMR it has been shown, that methane can be carbonylated with carbon monoxide to give acetic acid on solid acid catalyst, sulfated zirconia. The carbonylation occurs at 473−573 K with high selectivity and essential conversion. The reaction proceeds both in the absence and in the presence of molecular oxygen. In the presence of oxygen, the catalyst can be used for the carbonylation of further portion of methane without reactivation in air. The mechanism of the reaction is discussed. The reaction observed opens up new possibilities of using sulfated zirconia-based solid catalysts for the synthesis of acetic acid from methane and carbon monoxide.
Библиографическая ссылка:
Luzgin M.V.
, Rogov V.A.
, Kotsarenko N.S.
, Shmachkova V.P.
, Stepanov A.G.
Methane Carbonylation with CO on Sulfated Zirconia: Evidence from Solid-State NMR for the Selective Formation of Acetic Acid
The Journal of Physical Chemistry C. 2007. V.111. N28. P.10624-10629. DOI: 10.1021/jp0728757 WOS Scopus РИНЦ CAPlusCA OpenAlex
Methane Carbonylation with CO on Sulfated Zirconia: Evidence from Solid-State NMR for the Selective Formation of Acetic Acid
The Journal of Physical Chemistry C. 2007. V.111. N28. P.10624-10629. DOI: 10.1021/jp0728757 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 12 апр. 2007 г. |
| Принята к публикации: | 17 мая 2007 г. |
| Опубликована online: | 22 июн. 2007 г. |
| Опубликована в печати: | 1 июл. 2007 г. |
Идентификаторы БД:
| Web of science: | WOS:000247966700076 |
| Scopus: | 2-s2.0-34547538477 |
| РИНЦ: | 13550945 |
| Chemical Abstracts: | 2007:675060 |
| Chemical Abstracts (print): | 147:165845 |
| OpenAlex: | W2067792599 |