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Liquid-Phase Oxidation of α-Pinene with Oxygen Catalyzed by Carbon-Supported Platinum Metals Научная публикация

Журнал Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Вых. Данные Год: 2007, Том: 48, Номер: 1, Страницы: 38-44 Страниц : 7 DOI: 10.1134/S0023158407010065
Ключевые слова Platinum Catalyst; Platinum Metal; Sodium Formate; Verbenone; Allylic Oxidation
Авторы Kuznetsova L.I. 1 , Kuznetsova N.I. 1 , Lisitsyn A.S. 1 , Beck I.E. 1 , Likholobov V.A. 2 , Ancel J.E. 3
Организации
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia
2 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia
3 ARCHEMIS, 24 Avenue Jean Jaurés, 69153, Decines Charpieu Cédex, France

Информация о финансировании (1)

1 Совет по грантам Президента Российской Федерации НШ-2287.2003.3

Реферат: The liquid-phase oxidation of α-pinene with oxygen at 70–90°C is studied in the presence of Pd, Pt, Ru, Rh, and Ir supported on carbon. The conversion of α-pinene and the selectivity of formation of the main reaction products, namely, verbenol (1), verbenone (2), and α-pinene oxide (3), depends on the nature of the metal, on its oxidation state and extent of dispersion, and on the admixtures introduced into the system. In the presence of the Pt catalysts and promoting admixtures of tetrahexylammonium chloride (Hex4NCl), the selectivity of formation of the most valuable oxidation products (1 + 2) reaches 50% at an α-pinene conversion of 20–30%. The fraction of resinlike oxidation products decreases in the presence of the catalysts. The results obtained are discussed in the framework of the radical mechanism of α-pinene oxidation.
Библиографическая ссылка: Kuznetsova L.I. , Kuznetsova N.I. , Lisitsyn A.S. , Beck I.E. , Likholobov V.A. , Ancel J.E.
Liquid-Phase Oxidation of α-Pinene with Oxygen Catalyzed by Carbon-Supported Platinum Metals
Kinetics and Catalysis. 2007. V.48. N1. P.38-44. DOI: 10.1134/S0023158407010065 WOS Scopus РИНЦ CAPlusCA OpenAlex
Оригинальная: Кузнецова Л.И. , Кузнецова Н.И. , Лисицын А.С. , Бекк И.Э. , Лихолобов В.А. , Ансель Ж.-Э.
Жидкофазное окисление кислородом α-пинена, катализируемое нанесенными на углерод платиновыми металлами
Кинетика и катализ. 2007. Т.48. №1. С.44-50. РИНЦ
Даты:
Поступила в редакцию: 18 мар. 2005 г.
Опубликована в печати: 1 февр. 2007 г.
Идентификаторы БД:
Web of science: WOS:000244313200006
Scopus: 2-s2.0-33847224521
РИНЦ: 13554143
Chemical Abstracts: 2007:168740
Chemical Abstracts (print): 147:504191
OpenAlex: W1979228829
Цитирование в БД:
БД Цитирований
Web of science 8
Scopus 8
РИНЦ 8
OpenAlex 9
Альметрики: