Synthesis of Aluminum Oxides from the Products of the Rapid Thermal Decomposition of Hydrargillite in a Centrifugal Flash Reactor: II. Physicochemical Properties of the Products Obtained by the Centrifugal Thermal Activation of Hydrargillite | Sciact - CRIS-система Института катализа

Synthesis of Aluminum Oxides from the Products of the Rapid Thermal Decomposition of Hydrargillite in a Centrifugal Flash Reactor: II. Physicochemical Properties of the Products Obtained by the Centrifugal Thermal Activation of Hydrargillite Научная публикация

Журнал

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Вых. Данные

Год: 2007, Том: 48, Номер: 1, Страницы: 153-161 Страниц : 9 DOI: 10.1134/S002315840701020X

Ключевые слова

Aluminum Hydroxide; Boehmite; Bayerite; Thermal Dispersion; Dehydration Temperature

Авторы

Tanashev Yu.Yu. ¹ , Moroz E.M. ¹ , Isupova L.A. ¹ , Ivanova A.S. ¹ , Litvak G.S. ¹ , Amosov Yu.I. ¹ , Rudina N.A. ¹ , Shmakov A.N. ¹ , Stepanov A.G. ¹ , Kharina I.V. ¹ , Kul’ko E.V. ¹ , Danilevich V.V. ¹ , Balashov V. ¹ , Kruglyakov V.Y. ¹ , Zolotarskii I.A. ¹ , Parmon V.N. ¹

Организации

1	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

Информация о финансировании (3)

1	Сибирское отделение Российской академии наук	176
2	Президиум РАН
3	Президиум РАН	4.8

A variety of physicochemical methods were used to characterize the product of the rapid thermal decomposition of hydrargillite in a centrifugal flash reactor under the following conditions: the average particle size of the reactant, 80–120 μm; the temperature of the solid heating surface (plate or cylinder), 300–700°C; hot-zone residence time, ∼1 s; transfer of the product to the cooled zone of the reactor. The composition of the product and the extent of decomposition of hydrargillite were determined as a function of the processing temperature. The centrifugal thermal activation (CTA) of hydrargillite affords an X-ray-amorphous, highly reactive product with a developed surface and a disordered and inhomogeneous porous structure. This structure is capable of forming different modifications of aluminum hydroxide and oxide. The properties of the CTA product are compared with the properties of the earlier reported hydrargillite rapid decomposition products obtained using a gaseous heat-transfer agent (thermochemical activation product) or a fluidized bed of a granular heat-transfer agent (thermal dispersion product).

Tanashev Y.Y. , Moroz E.M. , Isupova L.A. , Ivanova A.S. , Litvak G.S. , Amosov Y.I. , Rudina N.A. , Shmakov A.N. , Stepanov A.G. , Kharina I.V. , Kul’ko E.V. , Danilevich V.V. , Balashov V. , Kruglyakov V.Y. , Zolotarskii I.A. , Parmon V.N.
Synthesis of Aluminum Oxides from the Products of the Rapid Thermal Decomposition of Hydrargillite in a Centrifugal Flash Reactor: II. Physicochemical Properties of the Products Obtained by the Centrifugal Thermal Activation of Hydrargillite
Kinetics and Catalysis. 2007. V.48. N1. P.153-161. DOI: 10.1134/S002315840701020X WOS Scopus РИНЦ CAPlusCA OpenAlex

Танашев Ю.Ю. , Мороз Э.М. , Исупова Л.А. , Иванова А.С. , Литвак Г.С. , Амосов Ю.И. , Рудина Н.А. , Шмаков А.Н. , Степанов А.Г. , Харина И.В. , Кулько Е.В. , Данилевич В.В. , Балашов В.А. , Кругляков В.Ю. , Золотарский И.А. , Пармон В.Н.
Получение оксидов алюминия на основе продуктов быстрого терморазложения гидраргиллита в центробежном флаш-реакторе. I. Физико-химические свойства продуктов центробежной термоактивации гидраргиллита
Кинетика и катализ. 2007. Т.48. №1. С.161-170. РИНЦ

Поступила в редакцию:	16 июн. 2005 г.
Опубликована в печати:	1 февр. 2007 г.

Web of science:	WOS:000244313200020
Scopus:	2-s2.0-33847210724
РИНЦ:	13537364
Chemical Abstracts:	2007:168765
Chemical Abstracts (print):	147:526467
OpenAlex:	W2313113635

БД	Цитирований
Web of science	30
Scopus	28
РИНЦ	29
OpenAlex	33