Effect of the Nature of the Active Component and Support on the Activity of Catalysts for the Hydrolysis of Sodium Borohydride | Sciact - CRIS-система Института катализа

Effect of the Nature of the Active Component and Support on the Activity of Catalysts for the Hydrolysis of Sodium Borohydride Научная публикация

Журнал

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Вых. Данные

Год: 2007, Том: 48, Номер: 1, Страницы: 168-175 Страниц : 8 DOI: 10.1134/S0023158407010223

Ключевые слова

Rhodium; Sodium Borohydride; Mechanical Mixture; Hydrogen Release; Rhodium Catalyst

Авторы

Simagina V.I. ¹ , Storozhenko P.A. ² , Netskina O.V. ¹ , Komova O.V. ¹ , Odegova G.V. ¹ , Samoilenko T.Yu. ¹ , Gentsler A.G. ¹

Организации

1	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia
2	State Research Institute of Chemistry and Technology of Organoelement Compounds, Moscow, 111123, Russia

Информация о финансировании (2)

1	Норильский никель
2	Российский фонд фундаментальных исследований	04-03-32208

The effect of the nature of an active component and a support on the rate of hydrolysis of aqueous sodium borohydride solutions was studied. It was found that the activity of supported catalysts, which were reduced in a reaction medium of sodium borohydride, decreased in the order Rh > Pt ≈ Ru ≫ Pd regardless of the nature of the support (γ-Al2O3, a Sibunit carbon material, or TiO2). The catalysts based on TiO2 exhibited the highest activity. As found by UV-vis diffuse reflectance spectroscopy, the composition and structure of the supported precursor of an active component depend on the nature of the support. It is likely that rhodium clusters with different reaction properties were formed on various supports under the action of a reaction medium.

Simagina V.I. , Storozhenko P.A. , Netskina O.V. , Komova O.V. , Odegova G.V. , Samoilenko T.Y. , Gentsler A.G.
Effect of the Nature of the Active Component and Support on the Activity of Catalysts for the Hydrolysis of Sodium Borohydride
Kinetics and Catalysis. 2007. V.48. N1. P.168-175. DOI: 10.1134/S0023158407010223 WOS Scopus РИНЦ CAPlusCA OpenAlex

Симагина В.И. , Стороженко П.А. , Нецкина О.В. , Комова О.В. , Одегова Г.В. , Самойленко Т.Ю. , Генцлер А.Г.
Влияние природы активного компонента и носителя на активность катализаторов гидролиза боргидрида натрия
Кинетика и катализ. 2007. Т.48. №1. С.177-184. РИНЦ

Поступила в редакцию:	28 окт. 2005 г.
Опубликована в печати:	1 февр. 2007 г.

Web of science:	WOS:000244313200022
Scopus:	2-s2.0-33847192152
РИНЦ:	13539232
Chemical Abstracts:	2007:168769
Chemical Abstracts (print):	146:366590
OpenAlex:	W2088927326

БД	Цитирований
Web of science	37
Scopus	39
РИНЦ	39
OpenAlex	39