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Reaction of CO Oxidation on Platinum, Rhodium, a Platinum–Rhodium Alloy, and a Heterophase Bimetallic Platinum/Rhodium Surface Научная публикация

Журнал Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Вых. Данные Год: 2007, Том: 48, Номер: 2, Страницы: 298-304 Страниц : 7 DOI: 10.1134/S0023158407020152
Ключевые слова Rhodium; Bimetallic Catalyst; Platinum Particle; Tantalum Foil; Bimetallic Sample
Авторы Kalinkin A.V. 1 , Pashis A.V. 1 , Bukhtiyarov V.I. 1
Организации
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

Реферат: The reaction of CO oxidation on thin metal films of platinum, rhodium, and their alloy and on a heterophase bimetallic Pt/Rh surface that consisted of platinum particles of size 10–20 nm on the surface of rhodium was studied in the region of low reactant pressures (lower than 2 × 10−5 mbar). At low temperatures (T < 200°C), the activity of samples increased in the order Rh > Pt/Rh > Pt-Rh alloy > Pt. Above 200°C, the rate of reaction on the heterophase Pt/Rh surface was almost twice as high as the sum of the rates of reaction on the individual metals; this fact is indicative of a synergistic effect. The nature of this effect is considered.
Библиографическая ссылка: Kalinkin A.V. , Pashis A.V. , Bukhtiyarov V.I.
Reaction of CO Oxidation on Platinum, Rhodium, a Platinum–Rhodium Alloy, and a Heterophase Bimetallic Platinum/Rhodium Surface
Kinetics and Catalysis. 2007. V.48. N2. P.298-304. DOI: 10.1134/S0023158407020152 WOS Scopus РИНЦ CAPlusCA OpenAlex
Оригинальная: Калинкин А.В. , Пашис А.В. , Бухтияров В.И.
Исследование реакции окисления СО на Pt, Rh, их сплаве и на гетерофазной биметаллической поверхности Pt/Rh
Кинетика и катализ. 2007. Т.48. №2. С.314-320. РИНЦ
Даты:
Поступила в редакцию: 27 дек. 2005 г.
Опубликована в печати: 1 мар. 2007 г.
Идентификаторы БД:
Web of science: WOS:000245978000015
Scopus: 2-s2.0-34247509613
РИНЦ: 13537700
Chemical Abstracts: 2007:452483
Chemical Abstracts (print): 147:151942
OpenAlex: W1993304204
Цитирование в БД:
БД Цитирований
Web of science 6
Scopus 6
РИНЦ 6
OpenAlex 10
Альметрики: