High-Temperature Carboxidation of Cyclopentene with Nitrous Oxide Full article
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Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2007, Volume: 48, Number: 3, Pages: 376-380 Pages count : 5 DOI: 10.1134/S0023158407030056 | ||
| Tags | Nitrous Oxide; Carbonyl Compound; Cyclopentene; Glutaric Acid; Cyclopentanone | ||
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Abstract:
It is demonstrated by the example of cyclopentene that the noncatalytic oxidation of alkenes with nitrous oxide to carbonyl compounds (carboxidation), which is known to occur in the liquid phase at 150–250°C, can also take place in the phase at higher temperatures (300–475°C). Like liquid-phase carboxidation, the gas-phase reaction likely proceeds via a dipolar 1,3-addition mechanism. However, 4-pentenal is formed along with cyclopentanone in the phase. The 4-pentenal selectivity increases from 2.5 to 23% as the reaction temperature is raised. High-temperature cyclopentene carboxidation can be carried out in a paraffin melt (bp ∼ 400°C). Filling the reactor with paraffin accelerates the reaction and reduces its activation energy.
Cite:
Starokonʹ E.V.
, Shubnikov K.S.
, Dubkov K.A.
, Kharitonov A.S.
, Panov G.I.
High-Temperature Carboxidation of Cyclopentene with Nitrous Oxide
Kinetics and Catalysis. 2007. V.48. N3. P.376-380. DOI: 10.1134/S0023158407030056 WOS Scopus РИНЦ ANCAN OpenAlex
High-Temperature Carboxidation of Cyclopentene with Nitrous Oxide
Kinetics and Catalysis. 2007. V.48. N3. P.376-380. DOI: 10.1134/S0023158407030056 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Староконь Е.В.
, Шубников К.С.
, Дубков К.А.
, Харитонов А.С.
, Панов Г.И.
Высокотемпературное карбоксидирование циклопентена закисью азота
Кинетика и катализ. 2007. Т.48. №3. С.397-402. РИНЦ
Высокотемпературное карбоксидирование циклопентена закисью азота
Кинетика и катализ. 2007. Т.48. №3. С.397-402. РИНЦ
Dates:
| Submitted: | Mar 23, 2006 |
| Published print: | May 1, 2007 |
Identifiers:
| Web of science: | WOS:000247416400005 |
| Scopus: | 2-s2.0-34250733914 |
| Elibrary: | 13548925 |
| Chemical Abstracts: | 2007:669045 |
| Chemical Abstracts (print): | 147:322513 |
| OpenAlex: | W1997228892 |