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Preparation and Characterization of Aluminosilicate Supports with a Synthesized Layer of Catalytic Filamentous Carbon: I. Synthesis of Carbon Nanofibers on a Supported Nickel Catalyst Full article

Journal Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Output data Year: 2007, Volume: 48, Number: 5, Pages: 749-756 Pages count : 8 DOI: 10.1134/S0023158407050217
Tags Foam; Pyrolysis; Cordierite; Nickel Hydroxide; Glass Foam
Authors Kovalenko G.A. 1 , Komova O.V. 1 , Chuenko T.V. 1 , Rudina N.A. 1 , Perminova L.V. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

Abstract: The synthesis of catalytic filamentous carbon (CFC) on a Ni catalyst supported by homogeneous precipitation onto the surface of aluminosilicate ceramic supports (honeycomb monoliths, ceramic foam, glass foam, and haydite) was studied. The effects of CFC synthesis conditions (the catalyst concentration on a support, the pyrolysis temperature of a propane-butane mixture, and the composition of the gas mixture) on the specific surface areas of supports, the yield of carbon, and the morphology of a surface CFC layer were examined. As found by scanning electron microscopy, the uniformity of distribution and the size of carbon nanofibers synthesized depended on the conditions of their synthesis. The resulting CFC-containing supports were tested as adsorbents for the immobilization of enzymatically active substances (individual enzymes, cell membranes, and microorganisms) in order to prepare highly stable heterogeneous catalysts for biotechnology and biocatalysis.
Cite: Kovalenko G.A. , Komova O.V. , Chuenko T.V. , Rudina N.A. , Perminova L.V.
Preparation and Characterization of Aluminosilicate Supports with a Synthesized Layer of Catalytic Filamentous Carbon: I. Synthesis of Carbon Nanofibers on a Supported Nickel Catalyst
Kinetics and Catalysis. 2007. V.48. N5. P.749-756. DOI: 10.1134/S0023158407050217 WOS Scopus РИНЦ ANCAN OpenAlex
Original: Коваленко Г.А. , Комова О.В. , Чуенко Т.В. , Рудина Н.А. , Перминова Л.В.
Приготовление и исследование алюмосиликатных носителей с синтезированным слоем каталитического волокнистого углерода. I. Синтез углеродных нановолокон на нанесенном Ni-катализаторе
Кинетика и катализ. 2007. Т.48. №5. С.800-807. РИНЦ
Dates:
Submitted: Jul 26, 2006
Published print: Sep 1, 2007
Identifiers:
Web of science: WOS:000249971500021
Scopus: 2-s2.0-35148900809
Elibrary: 13559407
Chemical Abstracts: 2007:1138049
Chemical Abstracts (print): 150:269065
OpenAlex: W2035678611
Citing:
DB Citing
Web of science 7
Scopus 5
Elibrary 5
OpenAlex 5
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