Defect Magnesium Oxides Containing Acetate and Nitrate Ion Fragments Incorporated in the Oxide Structure Full article
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Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2006, Volume: 47, Number: 3, Pages: 437-444 Pages count : 8 DOI: 10.1134/S0023158406030165 | ||
| Tags | Cation Vacancy; Acetate Group; Magnesium Hydroxide; Oxide Structure; Substitutional Solid Solution | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Council for Grants of the President of the Russian Federation | НШ-2120.2003.3 |
Abstract:
The results of studies on the synthesis of defect magnesium oxides by MgO hydration in salt solutions are summarized. The incorporation of oxygen-containing salt anions into the anionic hydroxide/oxide framework is described. In this case, the anion residue whose oxygen atoms belong to the oxygen framework of the oxide is incorporated in the octahedral oxygen cell of the oxide to occupy the place of a virtual magnesium cation. A portion of cationic vacancies remains free, whereas a portion is occupied by the transformed anion residue with a positive charge other than 2+. As a result, defect magnesium oxides are formed as substitutional solid solutions. The structure and charge heterogeneity of defect oxides is responsible for their high catalytic activity.
Cite:
Vasilʹeva N.A.
, Plyasova L.M.
, Odegova G.V.
Defect Magnesium Oxides Containing Acetate and Nitrate Ion Fragments Incorporated in the Oxide Structure
Kinetics and Catalysis. 2006. V.47. N3. P.437-444. DOI: 10.1134/S0023158406030165 WOS Scopus РИНЦ ANCAN OpenAlex
Defect Magnesium Oxides Containing Acetate and Nitrate Ion Fragments Incorporated in the Oxide Structure
Kinetics and Catalysis. 2006. V.47. N3. P.437-444. DOI: 10.1134/S0023158406030165 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Васильева Н.А.
, Плясова Л.М.
, Одегова Г.В.
Дефектные оксиды магния, содержащие встроенные в структуру оксида фрагменты ацетат- и нитрат-анионов
Кинетика и катализ. 2006. Т.47. №3. С.446-453. RSCI РИНЦ
Дефектные оксиды магния, содержащие встроенные в структуру оксида фрагменты ацетат- и нитрат-анионов
Кинетика и катализ. 2006. Т.47. №3. С.446-453. RSCI РИНЦ
Dates:
| Submitted: | Aug 16, 2004 |
| Published print: | May 1, 2006 |
Identifiers:
| Web of science: | WOS:000238264000016 |
| Scopus: | 2-s2.0-33747465523 |
| Elibrary: | 13517446 |
| Chemical Abstracts: | 2006:581110 |
| Chemical Abstracts (print): | 145:153457 |
| OpenAlex: | W2045233898 |