Composite Mechanism of the Catalytic Hydrogenation of Unsaturated Hydrocarbons on Hydrided Magnesium Intermetallides Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 2006, Volume: 47, Number: 5, Pages: 744-746 Pages count : 3 DOI: 10.1134/S0023158406050132 | ||
Tags | Hydride; Butadiene; Catalytic Hydrogenation; Unsaturated Hydrocarbon; Mechanochemical Activation | ||
Authors |
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Affiliations |
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Funding (2)
1 | Council for Grants of the President of the Russian Federation | НШ-2120.2003.3 |
2 | Russian Foundation for Basic Research | 02-03-32327 |
Abstract:
Two temperature ranges are distinguished in the catalytic hydrogenation of unsaturated hydrocarbons on magnesium intermetallide hydrides. In the lower temperature range, the reaction proceeds by a composite mechanism, as is indicated by the fact that the rate of the catalytic hydrogenation of ethylene, n-butenes, and butadiene is equal to the rate of the reduction of these hydrocarbons with hydride hydrogen. It is assumed that, at higher temperatures, the reaction proceeds by a heterogeneous-homogeneous mechanism.
Cite:
Molchanov V.V.
, Goidin V.V.
, Buyanov R.A.
Composite Mechanism of the Catalytic Hydrogenation of Unsaturated Hydrocarbons on Hydrided Magnesium Intermetallides
Kinetics and Catalysis. 2006. V.47. N5. P.744-746. DOI: 10.1134/S0023158406050132 WOS Scopus РИНЦ ANCAN OpenAlex
Composite Mechanism of the Catalytic Hydrogenation of Unsaturated Hydrocarbons on Hydrided Magnesium Intermetallides
Kinetics and Catalysis. 2006. V.47. N5. P.744-746. DOI: 10.1134/S0023158406050132 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Молчанов В.В.
, Гойдин В.В.
, Буянов Р.А.
Стадийный механизм каталитического гидрирования ненасыщенных углеводородов на гидридах интерметаллидов магния
Кинетика и катализ. 2006. Т.47. №5. С.767-769. RSCI РИНЦ
Стадийный механизм каталитического гидрирования ненасыщенных углеводородов на гидридах интерметаллидов магния
Кинетика и катализ. 2006. Т.47. №5. С.767-769. RSCI РИНЦ
Dates:
Submitted: | Jan 19, 2005 |
Published print: | Sep 1, 2006 |
Identifiers:
Web of science: | WOS:000241045200013 |
Scopus: | 2-s2.0-33749386766 |
Elibrary: | 13522083 |
Chemical Abstracts: | 2006:1026900 |
Chemical Abstracts (print): | 147:75349 |
OpenAlex: | W1982114887 |