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Effect of the Microstructure of Pt/CeO2–TiO2 Catalysts on Their Catalytic Properties in CO Oxidation Full article

Journal Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Output data Year: 2008, Volume: 49, Number: 2, Pages: 271-278 Pages count : 8 DOI: 10.1134/S0023158408020158
Tags Cerium; Cerium Oxide; Platinum Particle; Pore Volume Distribution; Platinum Cluster
Authors Shutilov A.A. 1 , Zenkovets G.A. 1 , Kryukova G.N. 1 , Gavrilov V.Yu. 1 , Paukshtis E.A. 1 , Boronin A.I. 1 , Koshcheev S.V. 1 , Tsybulya S.V. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

Abstract: The microstructure of 2% Pt/CeO2-TiO2 catalysts has an effect on their catalytic properties in CO oxidation. The nanostructured catalysts as platinum clusters 0.3–0.5 nm in size are the most active. These clusters are stabilized at crystal boundaries formed by irregularly intergrown anatase particles. The catalyst containing platinum particles 2–5 nm in size is less active because of the decrease in the extent of dispersion of platinum and the change of its electron state.
Cite: Shutilov A.A. , Zenkovets G.A. , Kryukova G.N. , Gavrilov V.Y. , Paukshtis E.A. , Boronin A.I. , Koshcheev S.V. , Tsybulya S.V.
Effect of the Microstructure of Pt/CeO2–TiO2 Catalysts on Their Catalytic Properties in CO Oxidation
Kinetics and Catalysis. 2008. V.49. N2. P.271-278. DOI: 10.1134/S0023158408020158 WOS Scopus РИНЦ ANCAN OpenAlex
Original: Шутилов А.А. , Зенковец Г.А. , Крюкова Г.Н. , Гаврилов В.Ю. , Паукштис Е.А. , Боронин А.И. , Кощеев С.В. , Цыбуля С.В.
Влияние микроструктуры катализаторов Pt/CeO2 TiO2 на каталитические свойства в реакции окисления СО
Кинетика и катализ. 2008. Т.49. №2. С.284-292. РИНЦ
Dates:
Submitted: Dec 11, 2006
Published print: Mar 1, 2008
Published online: Jan 20, 2011
Identifiers:
Web of science: WOS:000254964400015
Scopus: 2-s2.0-42149164950
Elibrary: 13592553
Chemical Abstracts: 2008:466793
Chemical Abstracts (print): 149:313918
OpenAlex: W2132852431
Citing:
DB Citing
Web of science 13
Scopus 11
Elibrary 11
OpenAlex 10
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