Stereoselective Hydrogenation of Acetylene on Copper Catalysts: A Quantum-Chemical Study Full article
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Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2008, Volume: 49, Number: 4, Pages: 527-530 Pages count : 4 DOI: 10.1134/S0023158408040113 | ||||
| Tags | High Occupied Molecular Orbital; Hydrogenation Reaction; Copper Surface; Copper Particle; Copper Catalyst | ||||
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Abstract:
The structure of the alkyne adsorption complex on the copper surface is favorable for the stereoselective formation of cis isomers in the hydrogenation reaction. The pathway of dissociative hydrogen adsorption on copper is reported. It is assumed that the electron-donating promoter acts to reduce the electron work function of the copper catalyst by partially covering or “decorating” the surface of the copper particles.
Cite:
Zhaksibaev M.Z.
, Malykhin S.E.
, Larichev Y.V.
, Pak A.M.
Stereoselective Hydrogenation of Acetylene on Copper Catalysts: A Quantum-Chemical Study
Kinetics and Catalysis. 2008. V.49. N4. P.527-530. DOI: 10.1134/S0023158408040113 WOS Scopus РИНЦ ANCAN OpenAlex
Stereoselective Hydrogenation of Acetylene on Copper Catalysts: A Quantum-Chemical Study
Kinetics and Catalysis. 2008. V.49. N4. P.527-530. DOI: 10.1134/S0023158408040113 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Жаксибаев М.Ж.
, Малыхин С.Е.
, Ларичев Ю.В.
, Пак А.М.
Изучение реакции стереоселективного гидрирования ацетилена на медных катализаторах методами квантовой химии
Кинетика и катализ. 2008. Т.49. №4. С.552-555. РИНЦ
Изучение реакции стереоселективного гидрирования ацетилена на медных катализаторах методами квантовой химии
Кинетика и катализ. 2008. Т.49. №4. С.552-555. РИНЦ
Dates:
| Submitted: | Sep 25, 2007 |
| Published print: | Jul 1, 2008 |
| Published online: | Aug 12, 2008 |
Identifiers:
| Web of science: | WOS:000258454900011 |
| Scopus: | 2-s2.0-49649084453 |
| Elibrary: | 13583923 |
| Chemical Abstracts: | 2008:971201 |
| Chemical Abstracts (print): | 150:143850 |
| OpenAlex: | W2043661447 |