The Dependence on Temperature and Concentration of 129Xe NMR Chemical Shift Values of Organoxenon(II) Salts [RXe][Y] and of the Parent Molecule XeF2 Full article
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Magnetic Resonance in Chemistry
ISSN: 0749-1581 , E-ISSN: 1097-458X |
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| Output data | Year: 2006, Volume: 44, Number: 6, Pages: 648-650 Pages count : 3 DOI: 10.1002/mrc.1799 | ||||
| Tags | 129Xe chemical shift values, 129Xe NMR, NMR, Organoxenon salts, Xenon difluoride | ||||
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Abstract:
The dependence of the 129Xe NMR chemical shift value of XeF2 on temperature and concentration was determined in a variety of prototypic media: in acidic (anhydrous HF, aHF), nonprotic but polar (dichloromethane), and basic (CD3CN-EtCN, 1:3 v/v) solvents. The 129Xe NMR spectra of a representative series of organoxenon(II) salts [RXe][Y] (R = C6F5, heptafluoro-1,4-cyclohexadien-1-yl (cyclo-1,4-C6F7), pentafluoro-1,4-cyclohexadien-3-on-1-yl (cyclo-3-O-1,4-C6F5), CF2 = C(CF3), (CF3)2CFC≡C, C4H9C≡C; Y = BF4, AsF6) in aHF showed, compared with XeF2[BOND]aHF, a quantitatively less distinct but qualitatively related dependence of δ(129Xe) vs temperature. The dependence of their δ(129Xe) values on concentration in aHF is negligible. An explanation for the different behavior of [RXe][Y] and XeF2 is offered.
Cite:
Bardin V.V.
, Frohn H-J.
The Dependence on Temperature and Concentration of 129Xe NMR Chemical Shift Values of Organoxenon(II) Salts [RXe][Y] and of the Parent Molecule XeF2
Magnetic Resonance in Chemistry. 2006. V.44. N6. P.648-650. DOI: 10.1002/mrc.1799 WOS Scopus РИНЦ ANCAN OpenAlex
The Dependence on Temperature and Concentration of 129Xe NMR Chemical Shift Values of Organoxenon(II) Salts [RXe][Y] and of the Parent Molecule XeF2
Magnetic Resonance in Chemistry. 2006. V.44. N6. P.648-650. DOI: 10.1002/mrc.1799 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Dec 6, 2005 |
| Accepted: | Jan 30, 2006 |
| Published online: | Mar 14, 2006 |
| Published print: | May 1, 2006 |
Identifiers:
| Web of science: | WOS:000237884900013 |
| Scopus: | 2-s2.0-33744478443 |
| Elibrary: | 13518950 |
| Chemical Abstracts: | 2006:582913 |
| Chemical Abstracts (print): | 145:223646 |
| OpenAlex: | W2087883457 |