Oxidation of the Polycrystalline Gold Foil Surface and XPS Study of Oxygen States in Oxide Layers Full article
| Journal |
Moscow University Chemistry Bulletin
ISSN: 0027-1314 , E-ISSN: 1935-0260 |
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| Output data | Year: 2007, Volume: 62, Number: 6, Pages: 343-349 Pages count : 7 DOI: 10.3103/S0027131407060090 | ||
| Tags | Gold Nanoparticles; Gold Surface; Oxygen State; Microwave Discharge; Gold Foil | ||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | The Ministry of Education and Science of the Russian Federation | 8051 |
| 2 | Zamaraev International Charitable Scientific Foundation |
Abstract:
Gold oxide films obtained on the surface of polycrystalline gold foil upon oxidation by oxygen activated by a high-frequency discharge have been studied by X-ray photoelectron spectroscopy. High-frequency O2 activation affords oxide films more than 3–5 nm thick. As follows from Au4f spectra, the surface gold atoms are oxidized to the oxidation state +3. The O1s spectra have a composite shape and are decomposed into four components that characterize nonequivalent states of oxygen in the resulting oxide films. It is assumed that the two major oxygen states (Eb(O1s) = 529.0 and 530.0 eV) correspond to the oxygen atoms in two-and three-dimensional gold oxide Au2O3, respectively. The oxygen states characterized by the higher binding energies (Eb(O1s) = 531.8 and 535.2 eV) likely correspond to molecular oxygen in peroxide and superoxide groups, respectively.
Cite:
Stadnichenko A.I.
, Koshcheev S.V.
, Boronin A.I.
Oxidation of the Polycrystalline Gold Foil Surface and XPS Study of Oxygen States in Oxide Layers
Moscow University Chemistry Bulletin. 2007. V.62. N6. P.343-349. DOI: 10.3103/S0027131407060090 WOS Scopus РИНЦ OpenAlex
Oxidation of the Polycrystalline Gold Foil Surface and XPS Study of Oxygen States in Oxide Layers
Moscow University Chemistry Bulletin. 2007. V.62. N6. P.343-349. DOI: 10.3103/S0027131407060090 WOS Scopus РИНЦ OpenAlex
Original:
Стадниченко А.И.
, Кощеев С.В.
, Боронин А.И.
Окисление поверхности массивного золота и исследование методом РФЭС состояний кислорода в составе оксидных слоев
Вестник Московского Университета. Серия 2: Химия. 2007. Т.48. №6. С.418-426. RSCI РИНЦ ANCAN
Окисление поверхности массивного золота и исследование методом РФЭС состояний кислорода в составе оксидных слоев
Вестник Московского Университета. Серия 2: Химия. 2007. Т.48. №6. С.418-426. RSCI РИНЦ ANCAN
Dates:
| Submitted: | Feb 20, 2007 |
| Published print: | Dec 1, 2007 |
Identifiers:
| Web of science: | WOS:000439735000009 |
| Scopus: | 2-s2.0-38849192557 |
| Elibrary: | 13565187 |
| OpenAlex: | W1999010728 |