Activation of Bis(pyrrolylaldiminato) and (Salicylaldiminato)(pyrrolylaldiminato) Titanium Polymerization Catalysts with Methylalumoxane | Sciact - CRIS-system of Boreskov Institute of Catalysis

Activation of Bis(pyrrolylaldiminato) and (Salicylaldiminato)(pyrrolylaldiminato) Titanium Polymerization Catalysts with Methylalumoxane Full article

Journal

Organometallics
ISSN: 0276-7333 , E-ISSN: 1520-6041

Output data

Year: 2007, Volume: 26, Number: 2, Pages: 288-293 Pages count : 6 DOI: 10.1021/om0607752

Tags

Aluminum; Catalysts; Molecular structure; Nuclear magnetic resonance spectroscopy; Olefins; Polymerization

Authors

Bryliakov Konstantin P. ¹ , Kravtsov Evgenii A. ¹ , Broomfield Lewis ² , Talsi Evgenii P. ¹ , Bochmann Manfred ²

Affiliations

1	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation
2	Wolfson Materials and Catalysis Centre, School of Chemical Sciences and Pharmacy, University of East Anglia, Norwich NR4 7TJ, United Kingdom

Funding (2)

1	Russian Foundation for Basic Research	06-03-32700
2	Royal Society	2004/R1-FSU

Activation of pyrollylaldiminato titanium complexes (N−N)2TiCl2 and of heteroligated (N−N)(N−O)TiCl2 with 13C-MAO leads to outer-sphere ion pairs [L‘LTiMe(S)]+[MeMAO]-, which rapidly polymerize 13C2H4. The catalysts show significant differences in deactivation pathways.

Bryliakov K.P. , Kravtsov E.A. , Broomfield L. , Talsi E.P. , Bochmann M.
Activation of Bis(pyrrolylaldiminato) and (Salicylaldiminato)(pyrrolylaldiminato) Titanium Polymerization Catalysts with Methylalumoxane
Organometallics. 2007. V.26. N2. P.288-293. DOI: 10.1021/om0607752 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Aug 25, 2006
Published online:	Dec 9, 2006
Published print:	Jan 1, 2007

Web of science:	WOS:000243339300007
Scopus:	2-s2.0-33846647018
Elibrary:	13558612
Chemical Abstracts:	2006:1288455
Chemical Abstracts (print):	146:206406
OpenAlex:	W2090245173

DB	Citing
Web of science	27
Scopus	28
Elibrary	28
OpenAlex	29