Structural Features and Transport Properties of La(Sr)Fe1-xNixO3-δ– Ce0.9Gd0.1O2-δ Nanocomposites—Advanced Materials for IT SOFC Cathodes | Sciact - CRIS-system of Boreskov Institute of Catalysis

Structural Features and Transport Properties of La(Sr)Fe1-xNixO3-δ– Ce0.9Gd0.1O2-δ Nanocomposites—Advanced Materials for IT SOFC Cathodes Full article

Conference

International Symposium on Innovative Materials for Processes in Energy Systems - For Fuel Cells, Heat Pumps and Sorption Systems
29 Nov - 1 Dec 2010 , Singapore

Journal

Heat Transfer Engineering
ISSN: 0145-7632 , E-ISSN: 1521-0537

Output data

Year: 2013, Volume: 34, Number: 11-12, Pages: 904-916 Pages count : 13 DOI: 10.1080/01457632.2012.752685

Tags

Electron spectroscopy; Isotopes; anocomposites; Nanocrystalline powders; Organic solvents; Oxygen; Perovskite; Photoelectrons; Sintering; Surface properties; Temperature programmed desorption; Transmission electron microscopy; Transport properties; X ray diffraction; X ray photoelectron spectroscopy

Authors

Pavlova Svetlana ¹ , Kharlamova Tamara ² , Sadykov Vladislav ¹ , Krieger Tamara ¹ , Muzykantov Vitaly ¹ , Bespalko Yulia ¹ , Ishchenko Arcady ¹ , Rogov Vladimir ¹ , Belyaev Vladimir ¹ , Okhlupin Yury ³ , Uvarov Nikolai ³ , Smirnova Alevtina ⁴

Affiliations

1	Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
2	Tomsk State University, Tomsk, Russia
3	Institute of Solid State Chemistry and Mechanochemistry of SB RAS, Novosibirsk, Russia
4	Environmental Earth Science Department, Eastern Connecticut State University, Willimantic, Connecticut, USA

Funding (4)

1	Siberian Branch of the Russian Academy of Sciences	57
2	The Ministry of Education and Science of the Russian Federation	14.740.12.1357
3	Президиум РАН	57
4	Национальная академия наук Беларуси	T09C-003

Mixed ionic−electronic conducting nanocomposites comprising complex oxides - perovskite (lanthanum-strontium nickelate-ferrite [LSFN]) and gadolinium-doped ceria (GDC) have been prepared via ultrasonic dispersion of nanocrystalline powders of LSFNx and GDC in organic solvent with addition of surfactant, followed by drying and sintering up to 1300°C. Their structural and surface properties have been studied by x-ray diffraction, ultraviolet–visible (UV-vis) electron spectroscopy, transmission electron microscopy with elemental analysis, and x-ray photoelectron spectroscopy. Results of impedance spectroscopy, oxygen isotope exchange, O2 temperature-programmed desorption, weight, and conductivity relaxation experiments have revealed a strong positive effect of perovskite−fluorite nanodomain interfaces in composite on the oxygen mobility and reactivity. Testing in wet H2/air feeds for a button-size cell with functionally graded LSFN0.4–GDC cathode layer supported on a thin YSZ layer covering Ni/YSZ cermet has demonstrated high and stable performance, promising for the practical application in the intermediate temperature range.

Pavlova S. , Kharlamova T. , Sadykov V. , Krieger T. , Muzykantov V. , Bespalko Y. , Ishchenko A. , Rogov V. , Belyaev V. , Okhlupin Y. , Uvarov N. , Smirnova A.
Structural Features and Transport Properties of La(Sr)Fe1-xNixO3-δ– Ce0.9Gd0.1O2-δ Nanocomposites—Advanced Materials for IT SOFC Cathodes
Heat Transfer Engineering. 2013. V.34. N11-12. P.904-916. DOI: 10.1080/01457632.2012.752685 WOS Scopus РИНЦ ANCAN OpenAlex

Accepted:	Feb 6, 2013
Published online:	Mar 13, 2013
Published print:	Sep 26, 2013

Web of science:	WOS:000327791700004
Scopus:	2-s2.0-84875401549
Elibrary:	20427922
Chemical Abstracts:	2013:222330
Chemical Abstracts (print):	160:343949
OpenAlex:	W1970204088

DB	Citing
Web of science	10
Scopus	10
Elibrary	9
OpenAlex	8